Optimization of Cuprous Oxides Thin Films to be used as Thermoelectric Touch Detectors

被引:27
作者
Figueira, Joana [1 ,2 ]
Loureiro, Joana [1 ,2 ]
Marques, Jose [1 ,2 ]
Bianchi, Catarina [1 ,2 ]
Duarte, Paulo [1 ,2 ]
Ruoho, Mikko [3 ]
Tittonen, Ilkka [3 ]
Ferreirat, Isabel [1 ,2 ]
机构
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, CENIMAT, I3N,Dept Ciencia Mat, P-2829516 Lisbon, Portugal
[2] Univ Nova Lisboa, UNINOVA, Fac Ciencias & Tecnol, Dept Ciencia Mat, P-2829516 Lisbon, Portugal
[3] Aalto Univ, Dept Micro & Nanosci, POB 13500, FI-00076 Aalto, Finland
基金
欧洲研究理事会;
关键词
copper oxide; Seebeck; thermal evaporation; thin films; postdeposition annealing; TRANSPARENT; NANOPARTICLES; FABRICATION; OXIDATION;
D O I
10.1021/acsami.6b12753
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The electronic and optical properties of p-type copper oxides (CO) strongly depend on the production technique as it influences the obtained phases: cuprous oxide (Cu2O) or cupric oxide (CuO), the most common ones. Cu films deposited by thermal evaporation have been annealed in air atmosphere, with temperature between 225 and 375 degrees C and time between 1 and 4 h. The resultant CO films have been studied to understand the influence of processing parameters in the thermoelectric, electrical, optical, morphological, and structural properties. Films with a Cu2O single phase are formed when annealing at 225 degrees C, while CuO single phase films can be obtained at 375 degrees C. In between, both phases are obtained in proportions that depend on the film thickness and annealing time. The positive sign of the Seebeck coefficient (S), measured at room temperature (RT), confirms the p-type behavior of both oxides, showing values up to 1.2 mV.degrees C-1 and conductivity up to 2.9 (Omega.m)(-1). A simple detector using Cu2O have been fabricated and tested with fast finger touch events.
引用
收藏
页码:6520 / 6529
页数:10
相关论文
共 37 条
[1]   Thin film deposition of Cu2O and application for solar cells [J].
Akimoto, K. ;
Ishizuka, S. ;
Yanagita, M. ;
Nawa, Y. ;
Paul, Goutam K. ;
Sakurai, T. .
SOLAR ENERGY, 2006, 80 (06) :715-722
[2]   Copper(I) oxide based thermoelectric powders and pastes with high Seebeck coefficients [J].
Andrei, Virgil ;
Bethke, Kevin ;
Rademann, Klaus .
APPLIED PHYSICS LETTERS, 2014, 105 (23)
[3]   Thermophysical characterization of a CuO thin deposit [J].
Battaglia, Jean-Luc ;
Kusiak, Andrzej .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2007, 28 (05) :1563-1577
[4]   V2O5 Thin Films for Flexible and High Sensitivity Transparent Temperature Sensor [J].
Bianchi, Catarina ;
Loureiro, Joana ;
Duarte, Paulo ;
Marques, Jose ;
Figueira, Joana ;
Ropio, Ines ;
Ferreira, Isabel .
ADVANCED MATERIALS TECHNOLOGIES, 2016, 1 (06)
[5]  
Biccari F., 2009, Defects and doping in Cu2O
[6]   Electrochemical synthesis and characterization of transparent nanocrystalline Cu2O films and their conversion to CuO films [J].
Brown, Kari E. R. ;
Choi, Kyoung-Shin .
CHEMICAL COMMUNICATIONS, 2006, (31) :3311-3313
[7]   The n-type conduction of indium-doped Cu2O thin films fabricated by direct current magnetron co-sputtering [J].
Cai, Xing-Min ;
Su, Xiao-Qiang ;
Ye, Fan ;
Wang, Huan ;
Tian, Xiao-Qing ;
Zhang, Dong-Ping ;
Fan, Ping ;
Luo, Jing-Ting ;
Zheng, Zhuang-Hao ;
Liang, Guang-Xing ;
Roy, V. A. L. .
APPLIED PHYSICS LETTERS, 2015, 107 (08)
[8]  
Carter B., 2007, CERAMIC MAT SCI ENG, V93, P538
[9]   Fabrication of Highly Transparent and Conductive Indium-Tin Oxide Thin Films with a High Figure of Merit via Solution Processing [J].
Chen, Zhangxian ;
Li, Wanchao ;
Li, Ran ;
Zhang, Yunfeng ;
Xu, Guoqin ;
Cheng, Hansong .
LANGMUIR, 2013, 29 (45) :13836-13842
[10]  
CIE, 2004, CIE15 2004 STAND ILL