Influence of Graphite Characteristics on the Electrochemical Performance in Alkylcarbonate LiTFSI Electrolyte for Li-Ion Capacitors and Li-Ion Batteries

被引:35
作者
Ghimbeu, Camelia Matei [1 ]
Decaux, Celine [2 ]
Brender, Patrice [1 ]
Dahbi, Mouad [3 ]
Lemordant, Daniel [3 ]
Raymundo-Pinero, Encarnacion [2 ]
Anouti, Meriem [3 ]
Beguin, Francois [2 ,4 ]
Vix-Guterl, Cathie [1 ]
机构
[1] UHA, CNRS, UMR 7361, IS2M, F-68057 Mulhouse, France
[2] Univ Orleans, CNRS, Ctr Rech Mat Divisee, F-45071 Orleans, France
[3] Univ Tours, F-37200 Tours, France
[4] Poznan Univ Tech, Inst Chem & Tech Electrochem, PL-60965 Poznan, Poland
关键词
CARBON NEGATIVE ELECTRODE; ACTIVE SURFACE-AREA; LITHIUM-ION; CHARGE LOSS; CYCLE PERFORMANCE; ANODE; IMPROVEMENT; REACTIVITY; CHEMISTRY; LI2FESIO4;
D O I
10.1149/2.101310jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This work presents the influence of some graphite physico-chemical characteristics such as morphology, structure, textural properties, surface functionality and active surface area (ASA) on the electrochemical performance. The reversible and irreversible capacities, SET formation at different charging rates, cycling ability have been determined using alkylcarbonate based electrolytes containing LiTFSI as main salt. Three families of graphites have been investigated by SEM, XRD, N-2 adsorption, Temperature Programmed Desorption (TPD-MS), and their physico-chemical properties have been correlated to some extent to their electrochemical performances. The irreversible capacity at first cycle increases with the active surface area (ASA) and the specific surface area. The applied current density plays an important role in the SET formation as shown by the reversible and irreversible capacities and the SEM observations. The passivation layer is mainly formed by polymeric species along with inorganic salts such as Li2CO3 or Li alkylcarbonates (ROLi) as revealed by XPS measurements. Nevertheless, very small quantities of LiTFSI degradation compounds have been detected (LiF, SOx) along with a reversible capacity fade. (C) 2013 The Electrochemical Society. All rights reserved.
引用
收藏
页码:A1907 / A1915
页数:9
相关论文
共 51 条
[1]   Analyses of capacity loss and improvement of cycle performance for a high-voltage hybrid electrochemical capacitor [J].
Aida, Taira ;
Murayama, Ichiro ;
Yamada, Koji ;
Morita, Masayuki .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (08) :A798-A804
[2]   Improvement in cycle performance of a high-voltage hybrid electrochemical capacitor [J].
Aida, Taira ;
Murayama, Ichiro ;
Yamada, Koji ;
Morita, Masayuki .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2007, 10 (04) :A93-A96
[3]   An asymmetric hybrid nonaqueous energy storage cell [J].
Amatucci, GG ;
Badway, F ;
Du Pasquier, A ;
Zheng, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (08) :A930-A939
[4]   Lithium-Ion Conducting Electrolyte Salts for Lithium Batteries [J].
Aravindan, Vanchiappan ;
Gnanaraj, Joe ;
Madhavi, Srinivasan ;
Liu, Hua-Kun .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (51) :14326-14346
[5]   On the behavior of different types of graphite anodes [J].
Aurbach, D ;
Teller, H ;
Koltypin, M ;
Levi, E .
JOURNAL OF POWER SOURCES, 2003, 119 :2-7
[6]   Failure and stabilization mechanisms of graphite electrodes [J].
Aurbach, D ;
Levi, MD ;
Levi, E ;
Schechter, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (12) :2195-2206
[7]   Correlation of the irreversible lithium capacity with the active surface area of modified carbons [J].
Béguin, F ;
Chevallier, F ;
Vix-Guterl, C ;
Saadallah, S ;
Bertagna, V ;
Rouzaud, JN ;
Frackowiak, E .
CARBON, 2005, 43 (10) :2160-2167
[8]   Influence of graphite surface properties on the first electrochemical lithium intercalation [J].
Bernardo, Ph. ;
Dentzer, J. ;
Gadiou, R. ;
Maerkle, W. ;
Goers, D. ;
Novak, P. ;
Spahr, M. E. ;
Vix-Guterl, C. .
CARBON, 2011, 49 (14) :4867-4876
[9]   Characterization of Carbon Surface Chemistry by Combined Temperature Programmed Desorption with in Situ X-ray Photoelectron Spectrometry and Temperature Programmed Desorption with Mass Spectrometry Analysis [J].
Brender, Patrice ;
Gadiou, Roger ;
Rietsch, Jean-Christophe ;
Fioux, Philippe ;
Dentzer, Joseph ;
Ponche, Arnaud ;
Vix-Guterl, Cathie .
ANALYTICAL CHEMISTRY, 2012, 84 (05) :2147-2153
[10]   How dynamic is the SEI? [J].
Bryngelsson, H. ;
Stjerndahl, M. ;
Gustafsson, T. ;
Edstrom, K. .
JOURNAL OF POWER SOURCES, 2007, 174 (02) :970-975