Application of ICP-MS and AFS to Detecting Heavy Metals in Phosphorus Fertilizers

被引：14
作者：
Huang Qing-qing [1 ]
Liu Xing [1 ]
Zhang Qian [1 ]
Qiao Yu-hui [1 ]
Su De-chun [1 ]
Jiang Rong-feng [1 ]
Rui Yu-kui [1 ]
Li Hua-fen [1 ]
机构：
[1] China Agr Univ, Coll Resources & Environm Sci, Beijing 100193, Peoples R China
来源：
SPECTROSCOPY AND SPECTRAL ANALYSIS | 2014年 / 34卷 / 05期
关键词：
Phosphorous fertilizers; Heavy metals; ICP-MS; AFS; PHOSPHATE FERTILIZERS; CADMIUM; SOILS; WHEAT;
D O I：
10.3964/j.issn.1000-0593(2014)05-1403-04
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
In order to investigate heavy metals in phosphorus fertilizers in China, 159 samples of phosphorus fertilizers including imported fertilizers and domestic fertilizers were collected from fertilizer markets, and the contents of heavy metals were determined by ICP-MS and AFS after microwave digestion. The results showed that the phosphorous fertilizers contained certain amount of heavy metals, and there was great variability in the contents of heavy metals. The mean contents of Cd, Cu, Zn, Cr, Pb, Ni, As and Hg were 0. 77, 35. 6, 102. 7, 24. 1, 16. 6, 15. 4, 19.4 and 0. 08 mg . kg(-1) fertilizer, respectively; based on the calculation of P2O5, the mean contents of above heavy metals were 4. 48, 258. 4, 767. 4, 190. 0, 151. 3, 134. 5, 155. 8 and 8. 79 mg . kg(-1) P2O5 respectively. The contents of heavy metals Cd, Cr, Pb, As and Hg in the tested samples accord with the ecological index of arsenic, cadmium, lead, chromium and mercury for fertilizers (GB/T 23349-2009), with the exception of Cd in one imported sample of diammonium phosphate and As in one sample of mono-ammonium phosphate. Analyzing the contents of heavy metals in imported fertilizers, the Cd contents in imported fertilizers was ranged from 0. 02 to 27. 2 mg . kg(-1) fertilizer, the mean and median Cd contents in imported fertilizers were 3. 20 and 0. 41 mg . kg(-1) fertilizer, respectively. And the Cu, Cr and Hg contents in the imported fertilizers were higher than that of domestic fertilizers, the mean contents of Cu, Cr and Hg in imported fertilizers were 39. 4, 26. 6 and 0. 47 mg . kg(-1) fertilizer, respectively.
引用
收藏
页码：1403 / 1406
页数：4
相关论文
共 15 条
[1]  
[陈芳 Chen Fang], 2005, [土壤, Soils], V37, P308
[2]   Heavy metal risk assessment for potatoes grown in overused phosphate-fertilized soils [J].
Cheraghi, Mehrdad ;
Lorestani, Bahareh ;
Merrikhpour, Hajar ;
Rouniasi, Nasim .
ENVIRONMENTAL MONITORING AND ASSESSMENT, 2013, 185 (02) :1825-1831
[3]   Modeling the cadmium balance in Australian agricultural systems in view of potential impacts on food and water quality [J].
de Vries, W. ;
McLaughlin, M. J. .
SCIENCE OF THE TOTAL ENVIRONMENT, 2013, 461 :240-257
[4]   Prediction of cadmium and zinc concentration in wheat grain from soils affected by the application of phosphate fertilizers varying in Cd concentration [J].
Francois, Matthieu ;
Grant, Cynthia ;
Lambert, Raphael ;
Sauve, Sebastien .
NUTRIENT CYCLING IN AGROECOSYSTEMS, 2009, 83 (02) :125-133
[5]   Spatial variability of soil total and DTPA-extractable cadmium caused by long-term application of phosphate fertilizers, crop rotation, and soil characteristics [J].
Jafarnejadi, A. R. ;
Sayyad, Gh ;
Homaee, M. ;
Davamei, A. H. .
ENVIRONMENTAL MONITORING AND ASSESSMENT, 2013, 185 (05) :4087-4096
[6]   CADMIUM STATUS OF SOILS AND PLANTS FROM A LONG-TERM FERTILITY EXPERIMENT IN SOUTHEAST NORWAY [J].
JENG, AS ;
SINGH, BR .
PLANT AND SOIL, 1995, 175 (01) :67-74
[7]  
LIU Shu-tang, 2005, J SOIL WATER CONSERV, V19, P64
[8]  
Lu Rukun, 1992, Acta Pedologica Sinica, V29, P150
[9]   An inventory of trace element inputs to agricultural soils in China [J].
Luo, Lei ;
Ma, Yibing ;
Zhang, Shuzhen ;
Wei, Dongpu ;
Zhu, Yong-Guan .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2009, 90 (08) :2524-2530
[10]   The influence of phosphate fertilizer application levels and cultivars on cadmium uptake by Komatsuna (Brassica rapa L. var. perviridis) [J].
Mar, Swe Swe ;
Okazaki, Masanori ;
Motobayashi, Takashi .
SOIL SCIENCE AND PLANT NUTRITION, 2012, 58 (04) :492-502
12