Magnetic and liquid crystalline property of long-alkyl chain appended iron (II) imidazole complexes

被引：6

作者：

Karim, Mohammad Razaul ^{[1
,2
]}

Takehira, Hiroshi ^{[2
]}

Rahman, Mohammed M. ^{[3
,4
]}

Asiri, Abdullah M. ^{[3
,4
]}

Amin, M. K. ^{[5
]}

Ohtani, Ryo ^{[2
]}

Hayami, Shinya ^{[2
]}

机构：

[1] Shahjalal Univ Sci & Technol, Sch Phys Sci, Dept Chem, Sylhet 3114, Bangladesh

[2] Kumamoto Univ, Grad Sch Sci & Technol, 2-39-1 Kurokami, Kumamoto 8608555, Japan

[3] King Abdulaziz Univ, CEAMR, POB 80203, Jeddah 21589, Saudi Arabia

[4] King Abdulaziz Univ, Dept Chem, POB 80203, Jeddah 21589, Saudi Arabia

[5] Khulna Univ, Khulna 9208, Bangladesh

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2016年 / 808卷

关键词：

Iron(II); 2-(2-Pyridyl)imidazole; Liquid crystal (LC); Spin crossover (SCO); C16-alkyl chain; SPIN-CROSSOVER; COBALT(II) COMPOUNDS; EQUILIBRIUM; DERIVATIVES; EXAMPLE;

D O I：

10.1016/j.jorganchem.2016.02.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fe[((py)im-C16)(3)](BF4)(2) (1) and Fe[((py)imH)(3)](BF4)(2) (2), the Iron(II) compounds with C16 long alkyl chain appended (py) imH and unmodified (py) imH [(py) imH = 2-(2-pyridyl)imidazole] have been synthesized and characterized by NMR, IR spectra and elemental analysis. For containing C16 long alkyl chain, complex 1 exhibits the liquid crystalline property around room temperature. The magnetic study suggests that 1 exists only in low spin state but 2 exhibits gradual spin crossover behavior. These observation suggests the possibility for synchronizing liquid crystallinity and spin crossover behavior of (py)imH complex in near future. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：42 / 47

页数：6

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