Polyoxometalate anion-π interaction-directed assembly of a three-dimensional hydrogen-bonded supramolecular framework with nanoscale porosity

被引：39

作者：

Liao, Jian-Zhen ^{[1
,2
]}

Dui, Xue-Jing ^{[1
,2
]}

Zhang, Hai-Long ^{[1
,2
]}

Wu, Xiao-Yuan ^{[1
]}

Lu, Can-Zhong ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

[3] Chinese Acad Sci, Key Lab Design & Assembly Funct Nanostruct, Beijing 100049, Peoples R China

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 46期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; CHARGE-TRANSFER; DIVERSITY; CHEMISTRY; RECEPTOR; DESIGN;

D O I：

10.1039/c4ce01283f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rare three-dimensional hydrogen-bonded supramolecular framework composed of octahedral [Cr(H3O)(3)(H2O)(3)](6+) ions and linear p-electron-deficient N,N'-di(4-pyridyl)-1,4,5,8-naphthalene-diimide (DPNDI) tectons was formed in the presence of electron-rich polyoxometalates by less common noncovalent anion-p interactions, indicating that polyoxometalates dominated self-assembly with anion-p interactions.

引用

页码：10530 / 10533

页数：4

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