Polyoxometalate anion-π interaction-directed assembly of a three-dimensional hydrogen-bonded supramolecular framework with nanoscale porosity

被引：39
|
作者：
Liao, Jian-Zhen [1 ,2 ]
Dui, Xue-Jing [1 ,2 ]
Zhang, Hai-Long [1 ,2 ]
Wu, Xiao-Yuan [1 ]
Lu, Can-Zhong [1 ,3 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
[3] Chinese Acad Sci, Key Lab Design & Assembly Funct Nanostruct, Beijing 100049, Peoples R China
来源：
CRYSTENGCOMM | 2014年 / 16卷 / 46期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; CHARGE-TRANSFER; DIVERSITY; CHEMISTRY; RECEPTOR; DESIGN;
D O I：
10.1039/c4ce01283f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A rare three-dimensional hydrogen-bonded supramolecular framework composed of octahedral [Cr(H3O)(3)(H2O)(3)](6+) ions and linear p-electron-deficient N,N'-di(4-pyridyl)-1,4,5,8-naphthalene-diimide (DPNDI) tectons was formed in the presence of electron-rich polyoxometalates by less common noncovalent anion-p interactions, indicating that polyoxometalates dominated self-assembly with anion-p interactions.
引用
收藏
页码：10530 / 10533
页数：4
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