Excess Enthalpies of Binary and Ternary Mixtures Containing Dibutyl Ether, Cyclohexane, and 1-Butanol at 298.15 K

被引:24
作者
Aguilar, Fernando [1 ]
Alaoui, Fatima E. M. [1 ]
Alonso-Tristan, Cristina [1 ]
Segovia, Jose J. [2 ]
Villamanan, Miguel A. [2 ]
Montero, Eduardo A. [1 ]
机构
[1] Univ Burgos, Escuela Politecn Super, Dept Ingn Electromecan, E-09006 Burgos, Spain
[2] Univ Valladolid, ETS Ingn Ind, Grp Termodinam & Calibrac TERMOCAL, E-47071 Valladolid, Spain
关键词
LIQUID-MIXTURES; HEXANE; THERMODYNAMICS; PREDICTION; 1-PROPANOL; VOLUMES; HEPTANE; OCTANE;
D O I
10.1021/je800751m
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental excess enthalpies of the ternary system dibutyl ether (DBE) + cyclohexane + I-butanol and the corresponding binary systems at 298.15 K are reported. A quasi-isothermal flow calorimeter has been built and tested to make the measurements. All the binary and the ternary systems show endothermic character. The experimental data have been fitted using a polynomial equation for the binary and ternary systems. The values of the standard deviation indicate good agreement between the experimental results and those calculated from the equation.
引用
收藏
页码:1672 / 1679
页数:8
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