Dinuclear half-sandwich complexes containing bridging 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligands.: Molecular structures of Cp2Fe2(CO)3[μ-Se2C2(B10H10)], Cp2Ru2[μ-S2C2(B10H10)]2, and CP*2Ru2(μ-Se)[μ-Se2C2(B10H10)].

被引:51
作者
Lu, SX
Jin, GX [1 ]
Eibl, S
Herberhold, M
Xin, Y
机构
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
[3] Univ Bayreuth, Anorgan Chem Lab, D-95440 Bayreuth, Germany
关键词
D O I
10.1021/om020022p
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Three prototypes of dinuclear complexes were obtained from the reactions of dilithium 1,2-dicarbacloso-dodecaborane-1,2-dichalcogenolates, (B10H10)C-2-(ELi)(2) (E = S, Se), with CpFe(CO)(2)Cl (1), CpRu(PPh3)(2)Cl (2), or [Cp*RuCl2](2) (3), respectively, and their structures have been determined by X-ray crystallography.
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页码:2533 / 2535
页数:3
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