Boron-nitrogen coordination polymers bearing ferrocene in the main chain

被引：91
作者：
Grosche, M
Herdtweck, E
Peters, F
Wagner, M
机构：
[1] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany
[2] Tech Univ Munich, Inst Anorgan Chem, D-85747 Munich, Germany
来源：
ORGANOMETALLICS | 1999年 / 18卷 / 22期
关键词：
D O I：
10.1021/om990594i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 1, 1'-fc(BMe2)(2) (2) with pyrazine gives a novel poly(ferrocene) [2.pyz](n), which has been. structurally characterized by X-ray crystallography [fc = (C5H4)(2)Fe; pyz = pyrazine]. The unusual dark green. color of the solid material is indicative of charge-transfer interactions between the iron centers and the electron-poor pyrazine adduct bridges.
引用
收藏
页码：4669 / 4672
页数：4
相关论文
共 23 条
[1]   SYSTEMATIC ANALYSIS OF STRUCTURAL DATA AS A RESEARCH TECHNIQUE IN ORGANIC-CHEMISTRY [J].
ALLEN, FH ;
KENNARD, O ;
TAYLOR, R .
ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (05) :146-153
[2]  
ALTOMARE A, 1992, SIR 92
[3]  
ARTUS G, 1994, STRUX 5 PROGRAM SYST
[4]   ACID-BASE PROPERTIES OF SOME PYRAZINES [J].
CHIA, AS ;
TRIMBLE, RF .
JOURNAL OF PHYSICAL CHEMISTRY, 1961, 65 (05) :863-&
[5]  
de Biani FF, 1997, INORG CHEM, V36, P2103
[6]  
Fontani M, 1998, EUR J INORG CHEM, P1453
[7]  
Fontani M, 1998, EUR J INORG CHEM, P2087
[8]   RING-OPENING POLYMERIZATION OF STRAINED, RING-TILTED FERROCENOPHANES - A ROUTE TO HIGH-MOLECULAR-WEIGHT POLY(FERROCENYLSILANES) [J].
FOUCHER, DA ;
TANG, BZ ;
MANNERS, I .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (15) :6246-6248
[9]  
Haines P.J., 1995, THERMAL METHODS ANAL
[10]   Sterically demanding ferrocene-based tris(1-pyrazolyl)borate ligands [J].
Herdtweck, E ;
Peters, F ;
Scherer, W ;
Wagner, M .
POLYHEDRON, 1998, 17 (07) :1149-1157
123