Synthesis, Structure and Electrochemical Properties of a Ferrocene-Bridged Bis[tris(arylselenolato)stannyl] Compound

被引：10
|
作者：
Nayek, Hari Pada [1 ,2 ]
Hilt, Gerhard [1 ,2 ]
Dehnen, Stefanie [1 ,2 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
[2] Univ Marburg, WZMW, D-35032 Marburg, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 28期
关键词：
Ferrocene; Selenium; Tin; X-ray diffraction; Cyclic voltammetry; DFT calculations; ORGANOTIN DERIVATIVES; TIN; ENERGY; APPROXIMATION; PALLADIUM(II); COMPLEXES; CLUSTER; CORE;
D O I：
10.1002/ejic.200900664
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two ferrocene-bridged bis[tris(arylselenolate)stannyl] compounds with the general formula (RSe)(3)Sn-Fc-Sn(SeR)(3) [Fc = ferrocene; R = Ph (1), 1-Np (2)] were synthesized and characterized by means of NMR spectroscopy (1, 2) as well as Xray diffraction (1). It was shown by DFT calculations that the observed mixed cis/trans conformation of the SePh groups in 1 represents the global minimum on the energy hyperface in the presence of an Fc bridge between the two tin atoms. Investigation of the electrochemical behavior of 1 indicated the electrochemically driven conversion under cleavage of the tin-selenium bond. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
引用
收藏
页码：4205 / 4208
页数：4
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