Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures

被引：41
|
作者：
Zhang, Keren [1 ]
Fahs, Gregory B. [1 ]
Aiba, Motohiro [1 ]
Moore, Robert B. [1 ]
Long, Timothy E. [1 ]
机构：
[1] Virginia Tech, Dept Chem, Macromol & Interfaces Inst, Blacksburg, VA 24061 USA
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 65期
基金：
美国国家科学基金会;
关键词：
RADICAL POLYMERIZATION; POLYMERS; ADENINE; RECOGNITION; THYMINE;
D O I：
10.1039/c4cc03363a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
RAFT polymerization afforded acrylic ABC triblock copolymers with self-complementary nucleobase-functionalized external blocks and a low-T-g soft central block. ABC triblock copolymers self-assembled into well-defined lamellar microphase-separated morphologies for potential applications as thermoplastic elastomers. Complementary hydrogen bonding within the hard phase facilitated self-assembly and enhanced mechanical performance.
引用
收藏
页码：9145 / 9148
页数：4
相关论文
共 50 条
  • [41] Hierarchical Sol-Gel Transition Induced by Thermosensitive Self-Assembly of an ABC Triblock Polymer in an Ionic Liquid
    Kitazawa, Yuzo
    Ueki, Takeshi
    McIntosh, Lucas D.
    Tamura, Saki
    Niitsuma, Kazuyuki
    Imaizumi, Satoru
    Lodge, Timothy P.
    Watanabe, Masayoshi
    MACROMOLECULES, 2016, 49 (04) : 1414 - 1423
  • [42] Synthesis and self-assembly behavior of thermoresponsive triblock copolymer
    Yu, Yueqin
    Li, Suhua
    Leng, Caifeng
    Xiong, Taizai
    Yuan, Kunshan
    Yan, Shaopeng
    Jia, Fuqiang
    POLYMER SCIENCE SERIES B, 2014, 56 (02) : 191 - 197
  • [43] Hydrogen-Bonding Interactions from Nucleobase-Decorated Supramolecular Polymer: Synthesis, Self-Assembly and Biomedical Applications
    Ilhami, Fasih Bintang
    Birhan, Yihenew Simegniew
    Cheng, Chih-Chia
    ACS BIOMATERIALS SCIENCE & ENGINEERING, 2023, 10 (01) : 234 - 254
  • [44] Controlled Self-Assembly of Photofunctional Supramolecular Nanotubes
    Cohen, Erez
    Weissman, Haim
    Pinkas, Iddo
    Shimoni, Eyal
    Rehak, Pavel
    Kral, Petr
    Rybtchinski, Boris
    ACS NANO, 2018, 12 (01) : 317 - 326
  • [45] Entropic Effects on the Supramolecular Self-Assembly of Macromolecules
    Pahnke, Kai
    Altintas, Ozcan
    Schmidt, Friedrich G.
    Barner-Kowollik, Christopher
    ACS MACRO LETTERS, 2015, 4 (07) : 774 - 777
  • [46] Self-Assembly of Symmetric Brush Diblock Copolymers
    Gu, Weiyin
    Huh, June
    Hong, Sung Woo
    Sveinbjornsson, Benjamin R.
    Park, Cheolmin
    Grubbs, Robert Howard
    Russell, Thomas P.
    ACS NANO, 2013, 7 (03) : 2551 - 2558
  • [47] Self-assembly of rod-coil-rod triblock copolymers: A route toward hierarchical liquid crystalline structures
    Li, Yongliang
    Jiang, Tao
    Wang, Liquan
    Lin, Shaoliang
    Lin, Jiaping
    POLYMER, 2016, 103 : 64 - 72
  • [48] Synthesis, characterization and pH-Responsive self-assembly behavior of amphiphilic multiarm star triblock copolymers based on PCL, PDEAEMA, and PEG
    Yang, You Qiang
    Lin, Wen Jing
    Zhang, Li Juan
    Cai, Cheng Zhi
    Jiang, Wei
    Guo, Xin Dong
    Qian, Yu
    MACROMOLECULAR RESEARCH, 2013, 21 (09) : 1011 - 1020
  • [49] SIMULATED ANNEALING STUDY OF THE SELF-ASSEMBLY OF END-ANCHORED ASYMMETRIC ABA TRIBLOCK COPOLYMERS IN SELECTIVE SOLVENTS
    Xu, Ji-hua
    Jiang, Run
    Yin, Yu-hua
    Wang, Zheng
    Li, Bao-hui
    ACTA POLYMERICA SINICA, 2013, (10) : 1277 - 1284
  • [50] RAFT preparation and self-assembly behavior of thermosensitive triblock PNIPAAm-b-PODA-b-PNIPAAm copolymers
    Wu, Jie
    Sun, Xuejiao
    Zhang, Ruling
    Yuan, Shichao
    Wu, Zongmei
    Lu, Qingliang
    Yu, Yueqin
    COLLOID AND POLYMER SCIENCE, 2016, 294 (12) : 1989 - 1995
12345