Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures

被引：41

作者：

Zhang, Keren ^{[1
]}

Fahs, Gregory B. ^{[1
]}

Aiba, Motohiro ^{[1
]}

Moore, Robert B. ^{[1
]}

Long, Timothy E. ^{[1
]}

机构：

[1] Virginia Tech, Dept Chem, Macromol & Interfaces Inst, Blacksburg, VA 24061 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 65期

基金：

美国国家科学基金会;

关键词：

RADICAL POLYMERIZATION; POLYMERS; ADENINE; RECOGNITION; THYMINE;

D O I：

10.1039/c4cc03363a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

RAFT polymerization afforded acrylic ABC triblock copolymers with self-complementary nucleobase-functionalized external blocks and a low-T-g soft central block. ABC triblock copolymers self-assembled into well-defined lamellar microphase-separated morphologies for potential applications as thermoplastic elastomers. Complementary hydrogen bonding within the hard phase facilitated self-assembly and enhanced mechanical performance.

引用

页码：9145 / 9148

页数：4

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