Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures

被引：41
|
作者：
Zhang, Keren [1 ]
Fahs, Gregory B. [1 ]
Aiba, Motohiro [1 ]
Moore, Robert B. [1 ]
Long, Timothy E. [1 ]
机构：
[1] Virginia Tech, Dept Chem, Macromol & Interfaces Inst, Blacksburg, VA 24061 USA
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 65期
基金：
美国国家科学基金会;
关键词：
RADICAL POLYMERIZATION; POLYMERS; ADENINE; RECOGNITION; THYMINE;
D O I：
10.1039/c4cc03363a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
RAFT polymerization afforded acrylic ABC triblock copolymers with self-complementary nucleobase-functionalized external blocks and a low-T-g soft central block. ABC triblock copolymers self-assembled into well-defined lamellar microphase-separated morphologies for potential applications as thermoplastic elastomers. Complementary hydrogen bonding within the hard phase facilitated self-assembly and enhanced mechanical performance.
引用
收藏
页码：9145 / 9148
页数：4
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