Synthesis, growth, crystal structure and characterization of a new organic NLO crystal: L-Lysine 4-nitrophenolate monohydrate (LLPNP)

被引：16
作者：
Mahadevan, M. [1 ,2 ]
Magesh, M. [3 ]
Ramachandran, K. [2 ]
Anandan, P. [4 ,5 ]
Arivanandhan, M. [4 ]
Hayakawa, Y. [4 ]
机构：
[1] Adhiparasakthi Engn Coll, Dept Phys, Melmaruvathur 603319, Tamil Nadu, India
[2] SRM Univ, Dept Phys, Madras 600026, Tamil Nadu, India
[3] Sri Sivasubramaniya Nadar Coll Engn, Ctr Crystal Growth, Madras 603110, Tamil Nadu, India
[4] Shizuoka Univ, Elect Res Inst, Naka Ku, Hamamatsu, Shizuoka 4328011, Japan
[5] Thiruvalluvar Coll Engn & Technol, Dept Phys, Vandavasi 604505, Tamil Nadu, India
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2014年 / 130卷
关键词：
Crystal growth; FTIR; NMR; Thermal analyses; Nonlinear optical; NONLINEAR-OPTICAL MATERIAL; SINGLE-CRYSTAL; ACID;
D O I：
10.1016/j.saa.2014.04.033
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
L-Lysine 4-nitrophenolate monohydrate (LLPNP) has been synthesized and grown by solution growth method at room temperature using deionised water as a solvent. The crystal structure of the materials was solved by single crystal X-ray diffraction analysis and it was found that the material has orthorhombic system. The crystallinity of the grown crystals was studied by the powder X-ray diffraction analysis. Molecular structure of the grown crystal was investigated by H-1 NMR spectroscopy. The various functional groups of the sample were identified by Fourier transform infrared and Fourier transform-Raman spectroscopic analyses. Thermal stability of the grown crystal has been studied by Thermogravimetric and Differential thermal (TG&DTA) analysis. The optical absorption of the grown crystals has been ascertained by UV-Vis-NIR absorption studies. Second harmonic generation (SHG) efficiency of the material has been determined by Kurtz and Perry technique and the efficiency was found to be 4.45 and 1.4 times greater than that of standard KDP and urea samples, respectively. (C) 2014 Elsevier B.V. All rights reserved.
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页码：416 / 422
页数：7
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