Synthesis, crystal structure and spectroscopic characterization of heterometallic Cu/Mo complexes obtained under mild conditions

被引：1

作者：

Buvailo, Halyna I. ^{[1
]}

Makhankova, Valeriya G. ^{[1
]}

Kokozay, Vladimir N. ^{[1
]}

Omelchenko, Iryna V. ^{[2
]}

Shishkina, Svitlana V. ^{[2
]}

Jezierska, Julia ^{[3
]}

机构：

[1] Taras Shevchenko Natl Univ Kyiv, Dept Inorgan Chem, 64 Volodymyrska St, UA-01601 Kiev, Ukraine

[2] Natl Acad Sci Ukraine, SSI Inst Single Crystals, 60 Nauky Ave, UA-61001 Kharkov, Ukraine

[3] Univ Wroclaw, Fac Chem, 14 F Joliot Curie, PL-50383 Wroclaw, Poland

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2018年 / 1167卷

关键词：

Heterometallic complexes; Molybdate; Crystal structure; EPR spectroscopy; 2,2'-BIPYRIDINE; COMPOUND; DATABASE; LIGANDS;

D O I：

10.1016/j.molstruc.2018.04.094

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two novel heterometallic compounds, namely, {[Cu(5,5'-Me(2)bpy)(2)](2)MoO4}(NO3)(2)center dot 3H(2)O (1) and [Cu(phen)(2)Mo2O7(phen)]center dot{[Cu(phen)(2)](2)MoO4}(NO3)(2)center dot 15H(2)O (2), where phen = 1,10-henantroline, 5,5'-Me(2)bpy = 5,5'-dimethyl-2,2'-bipyridine, have been isolated under mild conditions. The influence of the copper source and organic ligands on the products composition has been investigated. Both compounds were characterized by elemental, TG/DTA and single crystal X-ray diffraction analyses, IR and EPR spectroscopies. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：209 / 214

页数：6

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