Panchromatic absorbers for solar light-harvesting

被引:32
作者
Alexy, Eric J. [1 ]
Yuen, Jonathan M. [2 ]
Chandrashaker, Vanampally [1 ]
Diers, James R. [3 ]
Kirmaier, Christine [2 ]
Bocian, David F. [3 ]
Holten, Dewey [2 ]
Lindsey, Jonathan S. [1 ]
机构
[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA
[2] Washington Univ, Dept Chem, St Louis, MO 63130 USA
[3] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
关键词
PROBING ELECTRONIC COMMUNICATION; EXCITED-STATE PHOTODYNAMICS; PORPHYRIN; PERYLENE; DYADS; CELLS; BACTERIOCHLORIN; CHLORIN; IMIDES;
D O I
10.1039/c4cc06853j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A set of panchromatic absorbers exhibiting long excited-state lifetimes in both polar and nonpolar media has been prepared. The architectures are based on a porphyrin strongly coupled electronically to 1-4 perylene-monoimides via ethyne linkers. The constructs should find utility in molecular solar-conversion systems.
引用
收藏
页码:14512 / 14515
页数:4
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