Low-energy electron interactions with dimethyl disulphide

被引：3

作者：

Matias, C. ^{[1
,2
]}

Mauracher, A. ^{[1
,2
]}

Scheier, P. ^{[1
,2
]}

Limao-Vieira, P. ^{[3
]}

Denifl, S. ^{[1
,2
]}

机构：

[1] Univ Innsbruck, Inst Ionenphys & Angew Phys, A-6020 Innsbruck, Austria

[2] Univ Innsbruck, Ctr Mol Biosci Innsbruck, A-6020 Innsbruck, Austria

[3] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Fis, Lab Colisoes Atom & Mol,CEFITEC, P-2829516 Caparica, Portugal

来源：

CHEMICAL PHYSICS LETTERS | 2014年 / 605卷

关键词：

PHOTOABSORPTION CROSS-SECTION; AB-INITIO; ATTACHMENT;

D O I：

10.1016/j.cplett.2014.05.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron attachment experiments have been performed with dimethyl disulphide, C2H6S2, in the gas phase by means of a crossed electron-molecular beam experiment. Ion yields for 8 anions have been measured in the energy range from similar to 0 to 15 eV. Many of the dissociative electron attachment products observed at low energy arise from surprisingly complex reactions associated with multiple bond cleavages as well as structural and electronic rearrangement. Quantum chemical calculations on the electronic properties of C2H6S2 have been performed in order to complement the experimental investigations. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：71 / 76

页数：6

共 18 条

[1] Intramolecular Dynamics of RS-SR′ Systems (R, R′ = H, F, Cl, CH3, C2 H5): Torsional Potentials, Energy Levels, Partition Functions [J].