Palladium-Catalyzed Asymmetric Ring Opening Reaction of Azabenzonorbornadienes with Aromatic Amines

被引：40

作者：

Lu, Zhiwu ^{[1
]}

Wang, Jun ^{[2
]}

Han, Baiqiu ^{[1
]}

Li, Sifeng ^{[2
]}

Zhou, Yongyun ^{[1
]}

Fan, Baomin ^{[1
,3
]}

机构：

[1] Yunnan Minzu Univ, YMU HKBU Joint Lab Tradit Nat Med, Kunming 650500, Peoples R China

[2] South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China

[3] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2015年 / 357卷 / 14-15期

基金：

中国国家自然科学基金;

关键词：

amines; asymmetric ring opening reaction; azabenzonorbornadienes; palladium; silver; N-BOC-AZABENZONORBORNADIENE; SUBSTITUTED PIPERAZINE NUCLEOPHILES; ENANTIOSELECTIVE EPOXIDATION; AZABICYCLIC ALKENES; OXABENZONORBORNADIENES; LIGANDS; ANALOGS;

D O I：

10.1002/adsc.201500530

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A palladium/(R)-Binap catalyst for asymmetric ring opening reaction of azabenzonorbornadienes with amines was developed that afforded the corresponding substituted dihydronaphthalenes in good yields (up to 97%) with excellent enantioselectivities (up to > 99% ee). To the best of our knowledge, this represents the first palladium-catalyzed asymmetric ring opening reaction of azabenzonorbornadienes with heteronucleophiles.

引用

页码：3121 / 3125

页数：5

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