Luminescent Dinuclear Eu(III) Organic Complex as a Red-Emitting Phosphor for Fabrication of LEDs

被引:15
作者
He, Pei [1 ]
Wang, Huihui [1 ]
Liu, Shenggui [1 ]
Shi, Jianxin [1 ]
Wang, Gang [1 ]
Gong, Menglian [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Minist Educ, Lab Bioinorgan & Synthet Chem,State Key Lab Optoe, Guangzhou 510275, Guangdong, Peoples R China
关键词
europium compounds; gallium compounds; III-V semiconductors; indium compounds; light emitting diodes; organic compounds; phosphors; photoluminescence; thermal stability; DIODES; PHOTOLUMINESCENCE; PROGRESS;
D O I
10.1149/1.3082017
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A dinuclear Eu(III) organic complex, Eu-2(BTFBDEC)(3)(phen)(2), was synthesized, where BTFBDEC is 3,6-bis(4,4,4-trifluoro-1,3-butyldiketone)-9-ethyl-carbazole and phen is 1,10-phenanthroline. Eu-2(BTFBDEC)(3)(phen)(2) exhibits high thermal stability, excellent photoluminescence properties, appropriate CIE chromaticity coordinates for red and good quantum yield under near-UV light excitation. An intense red-emitting light-emitting diode (LED) was fabricated by combining Eu-2(BTFBDEC)(3)(phen)(2) with an similar to 395 nm emitting InGaN chip. The results indicate that Eu-2(BTFBDEC)(3)(phen)(2) is a good candidate as a red component for the fabrication of white LEDs.
引用
收藏
页码:B61 / B64
页数:4
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