Controlled deuterium labelling of imidazolium ionic liquids to probe the fine structure of the electrical double layer using neutron reflectometry

被引：11

作者：

Akutsu-Suyama, Kazuhiro ^{[1
]}

Cagnes, Marina ^{[2
]}

Tamura, Kazuhisa ^{[3
]}

Kanaya, Toshiji ^{[4
]}

Darwish, Tamim A. ^{[2
]}

机构：

[1] CROSS, Neutron Sci & Technol Ctr, 162-1 Shirakata, Tokai, Ibaraki 3191106, Japan

[2] Australian Nucl Sci & Technol Org, Australian Ctr Neutron Scattering & Natl Deuterat, Locked Bag 2001, Kirrawee Dc, NSW 2232, Australia

[3] Japan Atom Energy Agcy, Quantum Beam Sci Ctr, Sayo, Hyogo 6795148, Japan

[4] High Energy Accelerator Res Org, 203-1 Shirakata, Tokai, Ibaraki 3191106, Japan

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2019年 / 21卷 / 32期

关键词：

D EXCHANGE-REACTION; EFFICIENT; EXTRACTION; SCIENCE;

D O I：

10.1039/c9cp02479d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We combined the deuterium labeling and neutron reflectivity techniques to determine the fine structure of the electric double layer structure in an imidazolium ionic liquid (IL). For this, a simple and large scale deuteration method for imidazolium ILs was developed, where the deuteration level can be systematically controlled.

引用

页码：17512 / 17516

页数：5

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