Experimental and Theoretical Approach to Variable Chlorination-Promoted Skeletal Transformations in Fullerenes: The Case of C102

被引：20

作者：

Mazaleva, Olga N. ^{[1
]}

Ioffe, Ilya N. ^{[1
]}

Jin, Fei ^{[2
,3
]}

Yang, Shangfeng ^{[2
,3
]}

Kemnitz, Erhard ^{[4
]}

Troyanov, Sergey, I ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Chem Dept, Moscow 119991, Russia

[2] Univ Sci & Technol China, CAS Key Lab Mat Energy Convers, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[3] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China

[4] Humboldt Univ, Inst Chem, Brook Taylor Str 2, D-12489 Berlin, Germany

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 08期

基金：

俄罗斯基础研究基金会; 中国国家自然科学基金;

关键词：

C-2; LOSSES; C-86; FULLERENE; ISOMERS; C84CL30;

D O I：

10.1021/acs.inorgchem.7b02554

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of three alternative chlorination-promoted skeletal transformation pathways in the same fullerene cage is presented. Isolated-pentagon-rule (IPR) C-102(19) undergoes both Stone-Wales rotations to give non-IPR (C102Cl20)-C-#283794 and C-2 losses to form nonclassical C-98 and non-IPR C-96. X-ray structural characterization of the transformation products and a theoretical study of their formation pathways are reported.

引用

页码：4222 / 4225

页数：4

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