(Acetonitrile-N)(η4-2-methylbuta-1,3-diene)(η5-pentamethylcyclopentadienyl)-ruthenium(II) trifluoromethanesulfonate

被引：5
作者：
Gemel, C
Kirchner, K
Schmid, R
Mereiter, K
机构：
[1] Tech Univ Vienna, Inst Inorgan Chem, A-1060 Vienna, Austria
[2] Tech Univ Vienna, Inst Mineral Crystallog & Struct Chem, A-1060 Vienna, Austria
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270199012342
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Ru{eta(5)-C-5(CH3)(5)}{eta(4)-CH2C(CH3)CHCH2}(CH3CN)](CF3SO3) or [Ru(C5H8)(C10H15)(C2H3N)](CF3SO3), contains a half-sandwich ruthenium complex with an exo-oriented pi-bonded diene moiety inclined at an angle of 16.0(2)degrees to the cyclopentadienyl ring. The coordination geometry of ruthenium can be described as a three-legged piano stool.
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页码：2053 / 2055
页数：3
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