The use of ion exchange in the recovery of vanadium from the mass of a spent catalyst used in the oxidation of SO2 to SO3

被引:6
作者
Druzynski, Sebastian [1 ]
Mazurek, Krzysztof [1 ]
Bialowicz, Katarzyna [1 ]
机构
[1] Nicholas Copernicus Univ, Fac Chem, Dept Chem Technol, PL-87100 Torun, Poland
关键词
spent vanadium catalyst; recovery of vanadium; ion exchange; solid waste utilization; MEMBRANE; EXTRACTION; POTASSIUM; HCL;
D O I
10.2478/pjct-2014-0032
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In the studies on the recovery of vanadium from vanadium catalyst extracts, three types of polymer strongly acidic ion exchangers were used. The ion exchange resins differed in terms of granularity and their ion exchange capacity. As a result, breakthrough curves were made for three main components of the test extract, i.e.: ions of vanadium, iron and potassium. On this basis the optimum conditions for the removal of iron ions from the solution were defined and the technological concept of the process in the semi-technical scale was proposed.
引用
收藏
页码:69 / 73
页数:5
相关论文
共 15 条
[1]  
Aniol S., 1997, POL J APPL CHEM, V41, P25
[2]  
Grzesiak P., 2004, SULFURIC ACID NEW OP
[3]  
Grzesiak P., 2004, Development of Sulfuric Acid Production in Poland
[4]   Recovery of vanadium, potassium and iron from a spent catalyst using urea solution [J].
Mazurek, Krzysztof ;
Bialowicz, Katarzyna ;
Trypuc, Mieczyslaw .
HYDROMETALLURGY, 2010, 103 (1-4) :19-24
[5]   Extraction of vanadium compounds from the used vanadium catalyst with the potassium hydroxide solution [J].
Mazurek, Krzysztof ;
Bialowicz, Katarzyna ;
Trypuc, Mieczyslaw .
POLISH JOURNAL OF CHEMICAL TECHNOLOGY, 2010, 12 (01) :23-28
[6]  
Mazurek K, 2009, PRZEM CHEM, V88, P1248
[7]   Column performance in lead removal from aqueous solutions by fixed bed of natural zeolite-clinoptilolite [J].
Medvidovic, N. Vukojevic ;
Peric, J. ;
Trgo, M. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2006, 49 (03) :237-244
[8]   SIMPLIFIED METHOD OF INTERPRETING KINETIC DATA IN FIXED-BED ION EXCHANGE [J].
MICHAELS, AS .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1952, 44 (08) :1922-1930
[9]   Vanadium recovery from oil fly ash by leaching, precipitation and solvent extraction processes [J].
Navarro, R. ;
Guzman, J. ;
Saucedo, I. ;
Revilla, J. ;
Guibal, E. .
WASTE MANAGEMENT, 2007, 27 (03) :425-438
[10]   Metal extraction from spent sulfuric acid catalyst through alkaline and acidic leaching [J].
Ognyanova, A. ;
Ozturk, A. T. ;
De Michelis, I. ;
Ferella, F. ;
Taglieri, G. ;
Akcil, A. ;
Veglio, F. .
HYDROMETALLURGY, 2009, 100 (1-2) :20-28