Two Cadmium(II) Complexes of an Acylhydrazone Ligand Bearing Quinoline Unit: Syntheses, Structures and Fluorescent Properties

被引：0

作者：

Li Xiao-Jing ^{[1
]}

Wu Wei-Na ^{[1
]}

Xu Zhou-Qing ^{[1
]}

Li Shou-Jie ^{[1
]}

Zhao Liang ^{[1
]}

机构：

[1] Henan Polytech Univ, Dept Phys & Chem, Jiaozuo 454000, Henan, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 31卷 / 11期

关键词：

quinoline; Cd(II) complex; fluorescence; crystal structure; thermostability; CRYSTAL-STRUCTURE; CU(II) COMPLEXES; BIOLOGICAL-ACTIVITIES; METAL-COMPLEXES;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two complexes [Cd (L) (H2O) (NO3)(2)] (1) and [Cd (L)I-2]center dot CH3OH (2) (L = 4-hydroxy-N-((quinolin-8-yl) methylene)benzohydrazide) have been synthesized and structurally determined by single-crystal X-ray diffraction. The results show that the Cd(1) ion in 1 with a mono-capped trigonal prismatic geometry is surrounded by one acylhydrazone ligand with N2O donor set, one water molecule, one mono-dendate and one bidendate nitrate anions. However, the coordination geometry of the Cd(I) ion in 2 is a distorted tetragonal pyramid with oxygen and two nitrogen atoms provided by the ligand L and two iodide anions. The thermal stabilities and luminescent properties of both complexes are also investigated in detail. CCDC: 1034567, 1; 1405135, 2.

引用

页码：2265 / 2271

页数：7

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