Electroactive films of poly(tetraphenylporphyrins) with reduced bandgap

被引：49
作者：
Paul-Roth, Christine
Rault-Berthelot, Joelle
Simonneaux, Gerard
Poriel, Cyril
Abdalilah, Mohammed
Letessier, Julien
机构：
[1] Univ Rennes 1, ICMV, CNRS, Lab Sci Chim Rennes,UMR 6226, F-35042 Rennes, France
[2] Univ Rennes 1, MaCSE, CNRS, Lab Sci Chim Rennes,UMR 6226, F-35042 Rennes, France
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2006年 / 597卷 / 01期
关键词：
anodic electrodeposition; meso-tetraphenyl-porphyrin; modified electrode; electrogenerated polymer;
D O I：
10.1016/j.jelechem.2006.07.039
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The anodic oxidation of tetraphenylporphyrins (ZnTPP and H2TPP) in CH2Cl2 + Bu4NPF6 (0.2 M) leads to the coverage of the electrode by insoluble electroactive deposits. These new films possess interesting electrochemical behaviour with a low redox bandgap between their oxidation and reduction processes. [GRAPHICS] (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：19 / 27
页数：9
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