Homogeneous modeling of ammoxidation chemistry: nitrile formation using a soluble analogue of MoO3

被引：16

作者：

Mohs, TR ^{[1
]}

Du, YH ^{[1
]}

Plashko, B ^{[1
]}

Maatta, EA ^{[1
]}

机构：

[1] KANSAS STATE UNIV,DEPT CHEM,MANHATTAN,KS 66506

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a703790b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the soluble MoO3 analogue [Mo6O19](2-) with Ph3P=NCH2Ph replicates key features of heterogeneous ammoxidation chemistry by producing moderate yields of PhC=N through the proposed intermediacy of the benzylimido hexamolybdate complex [Mo6O18(NCH2Ph)](2-).

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收藏

页码：1707 / 1708

页数：2

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