A new 1D metal-organic coordination polymer with blue fluorescent emission:: [Cd2(1,10′-phen)2(betc)(H2O)]n

被引：20
作者：
Gu, XJ
Chen, YH
Peng, J [1 ]
Shi, ZY
Wang, E
Hu, NH
机构：
[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 697卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
benzene-1,2,3,4,5-tetracarboxylate; hydrothermal synthesis; coordination polymer; fluorescent emission;
D O I：
10.1016/j.molstruc.2004.04.015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new coordination polymer [Cd-2(1,10'-phen)(2)(betc)(H2O)](n) (1) (betc = benzene-1,2,4,5-tetracarboxylate, 1,10'-phen = 1,10'-phenanthroline) was hydrothermally synthesized from CdCl2.2.5H(2)O, H(4)betc and 1,10'-phen at 160 degreesC. It was characterized by IR, XPS, TG and single-crystal X-ray diffraction. Compound 1 possesses infinite chair-like chains which construct 3D framework through pi-pi interactions and the hydrogen bond interactions. The fluorescent spectrum study shows that compound 1 exhibits blue fluorescent emission in the solid at room temperature. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：231 / 235
页数：5
相关论文
共 25 条
  • [11] Self-assembly of discrete cyclic nanostructures mediated by transition metals
    Leininger, S
    Olenyuk, B
    Stang, PJ
    [J]. CHEMICAL REVIEWS, 2000, 100 (03) : 853 - 907
  • [12] New two-dimensional metal-organic networks constructed from 1,2,4,5-benzenetetracarboxylate and chelate ligands
    Li, YG
    Hao, N
    Lu, Y
    Wang, EB
    Kang, ZH
    Hu, CW
    [J]. INORGANIC CHEMISTRY, 2003, 42 (09) : 3119 - 3124
  • [13] A novel octupolar metal-organic NLO material based on a chiral 2D coordination network
    Lin, WB
    Wang, ZY
    Ma, L
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (48) : 11249 - 11250
  • [14] From molecules to crystal engineering: Supramolecular isomerism and polymorphism in network solids
    Moulton, B
    Zaworotko, MJ
    [J]. CHEMICAL REVIEWS, 2001, 101 (06) : 1629 - 1658
  • [15] Noro S, 2000, ANGEW CHEM INT EDIT, V39, P2082
  • [16] RPM-1: A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption
    Pan, L
    Liu, HM
    Lei, XG
    Huang, XY
    Olson, DH
    Turro, NJ
    Li, J
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (05) : 542 - +
  • [17] Synthesis and structure of the first open-framework cadmium oxalate possessing channels
    Prasad, PA
    Neeraj, S
    Natarajan, S
    Rao, CNR
    [J]. CHEMICAL COMMUNICATIONS, 2000, (14) : 1251 - 1252
  • [18] Sheldrick G.M., 1997, Programs for Crystal Structure Analysis (Release 97-2)
  • [19] Solvothermal syntheses and crystal structures of two metal coordination polymers with double-chain structures
    Shi, Q
    Cao, R
    Sun, DF
    Hong, MC
    Liang, YC
    [J]. POLYHEDRON, 2001, 20 (28) : 3287 - 3293
  • [20] A novel organic-inorganic hybrid material with fluorescent emission:: [Cd(PT)(H2O)]n (PT = phthalate)
    Wang, ST
    Hou, Y
    Wang, EB
    Li, YG
    Xu, L
    Peng, J
    Liu, SX
    Hu, CW
    [J]. NEW JOURNAL OF CHEMISTRY, 2003, 27 (07) : 1144 - 1147
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