A new 1D metal-organic coordination polymer with blue fluorescent emission:: [Cd2(1,10′-phen)2(betc)(H2O)]n

被引：20
作者：
Gu, XJ
Chen, YH
Peng, J [1 ]
Shi, ZY
Wang, E
Hu, NH
机构：
[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 697卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
benzene-1,2,3,4,5-tetracarboxylate; hydrothermal synthesis; coordination polymer; fluorescent emission;
D O I：
10.1016/j.molstruc.2004.04.015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new coordination polymer [Cd-2(1,10'-phen)(2)(betc)(H2O)](n) (1) (betc = benzene-1,2,4,5-tetracarboxylate, 1,10'-phen = 1,10'-phenanthroline) was hydrothermally synthesized from CdCl2.2.5H(2)O, H(4)betc and 1,10'-phen at 160 degreesC. It was characterized by IR, XPS, TG and single-crystal X-ray diffraction. Compound 1 possesses infinite chair-like chains which construct 3D framework through pi-pi interactions and the hydrogen bond interactions. The fluorescent spectrum study shows that compound 1 exhibits blue fluorescent emission in the solid at room temperature. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：231 / 235
页数：5
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