Synthesis of a Biodegradable Material Poly (lactic acid-co-melamine) via Direct Melt Polycondensation

被引：0

作者：

Feng, Minhua ^{[1
]}

Xiong, Jinfeng ^{[1
]}

Wang, Qunfang ^{[1
]}

Wang, Zhaoyang ^{[1
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China

来源：

ADVANCES IN CHEMICAL ENGINEERING III, PTS 1-4 | 2013年 / 781-784卷

关键词：

Biodegradable material; Copolymer; Star-shaped Poly(lactic acid) (SPLA); D; L-lactic acid (D; L-LA); Direct Melt Polycondensation; Synthesis; POLY(LACTIC ACID); FLAME-RETARDANT; COPOLYCONDENSATION;

D O I：

10.4028/www.scientific.net/AMR.781-784.503

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Directly starting from D,L-lactic acid (LA) and melamine (MA), novel star-shaped biodegradable material poly(lactic acid-co-melamine) [P(LA-co-MA)] as a kind of potential flame retardant is synthesized via melt polycondensation. When the molar feed ratio n(LA)/n(MA) is 60/1, the optimal synthetic conditions are discussed. After the prepolymerization at 140 degrees C for 8 h, using 0.4 wt % stannous chloride as the catalyst, the melt copolymerization at 160 degrees C for 8 h gives the copolymer with the biggest intrinsic viscosity 0.87 dL.g(-1).

引用

页码：503 / 506

页数：4

共 27 条

[1] Star-shaped poly(lactic acid) with carboxylic acid terminal groups via poly-condensation [J].

Abiko, Atsushi ;

Yano, Shin-ya ;

Iguchi, Makoto .

POLYMER, 2012, 53 (18) :3842-3848

[2] Synthesis and characterization of a novel biodegradable polymer poly(lactic acid-glycolic acid-4-hydroxyproline) [J].

Duan, Jiufang ;

Du, Jie ;

Zheng, Yubin .

JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (06) :3585-3590

[3] An intumescent flame retardant system using β-cyclodextrin as a carbon source in polylactic acid (PLA) [J].

Feng, Jian-Xiang ;

Su, Sheng-Pei ;

Zhu, Jin .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2011, 22 (07) :1115-1122

[4] Study on preparation and fire-retardant mechanism analysis of intumescent flame-retardant coatings [J].

Gu, Jun-wei ;

Zhang, Guang-cheng ;

Dong, Shan-lai ;

Zhang, Qiu-yu ;

Kong, Jie .

SURFACE & COATINGS TECHNOLOGY, 2007, 201 (18) :7835-7841

[5] Synthesis and characterization of star-shaped poly(ethylene glycol)-block-poly(L-lactic acid) copolymers by melt polycondensation [J].

Lin, Yaling ;

Zhang, Anqiang ;

Wang, Lianshi .

JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 124 (06) :4496-4501

[6] Synthesis of biodegradable material poly(lactic acid-co-sorbitol) via direct melt polycondensation and its reaction mechanism [J].

Luo, Shi-He ;

Wang, Qun-Fang ;

Xiong, Jin-Feng ;

Wang, Zhao-Yang .

JOURNAL OF POLYMER RESEARCH, 2012, 19 (09)

[7] Synthesis of biodegradable material poly(lactic acid-co-glycerol) via direct melt polycondensation and its reaction mechanism [J].

Luo, Shi-He ;

Wang, Zhao-Yang ;

Mao, Chao-Xu ;

Huo, Jing-Pei .

JOURNAL OF POLYMER RESEARCH, 2011, 18 (06) :2093-2102

[8] Research on the Modification of Poly(L-lactic acid) by Glucose via Direct Melt Polycondensation [J].

Luo, Shihe ;

Yu, Shiqin ;

Li, Jianxiao ;

Wang, Zhaoyang .

ADVANCED MATERIALS AND PROCESSES, PTS 1-3, 2011, 311-313 :1106-1109

[9] Synthesis of Poly(D,L-lactic acid-co-Glucose) via Direct Polycondensation and its Characterization [J].

Luo, Shihe ;

Wang, Zhaoyang ;

Huang, Dongna ;

Mao, Chaoxu ;

Xiong, Jinfeng .

INFORMATION ENGINEERING FOR MECHANICS AND MATERIALS SCIENCE, PTS 1 AND 2, 2011, 80-81 :370-374

[10] Synthesis of Poly(D, L-lactic acid) Modified by Triethanolamine by Direct Melt Copolycondensation and Its Characterization [J].

Luo, Yu-Fen ;

Wang, Zhao-Yang ;

Ye, Rui-Rong ;

Luo, Shi-He ;

Yang, Li-Ting .

JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 119 (04) :1883-1888

← 1 2 3 →