Anomalous red luminescence of Sm3+ ions in Sm3+:LaKNaTaO5 single crystals

被引:15
作者
Korzeniowski, Kamil [1 ]
Sobczyk, Marcin [1 ]
机构
[1] Univ Wroclaw, Fac Chem, Ul F Joliot Curie 14, PL-50383 Wroclaw, Poland
关键词
Sm3(+); Tantalates; Luminescence; Red phosphors; OPTICAL-PROPERTIES; SM3+; PHOSPHORS; GLASSES; LASER;
D O I
10.1016/j.ssc.2018.02.003
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
For the first time much more intense (4)G(5/2) -> H-6(9/2) transition than others (4)G(5/2) -> H-6(J/2) transitions of the Sm3+ doped oxides have been observed. The Sm3+-doped LaKNaTaO5 single crystals have been grown by the flux growth method. The emission and excitation spectra as well as decay profiles of the (4)G(5/2) luminescent level of the Sm3+ ion have been measured. The decay curve has been fitted by the Inokuti-Hirayama energy transfer model which revealed that electric dipole-dipole interaction is responsible for the energy transfer processes in the Sm3+:LaKNaTaO5 single crystals. The title phosphors may be potentially used as red phosphor for white light-emitting diodes.
引用
收藏
页码:30 / 33
页数:4
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