Unexpected Secoiridoid Glucosides from Manulea corymbosa

被引：13

作者：

Gousiadou, Chrysoula ^{[1
]}

Kokubun, Tetsuo ^{[2
]}

Gotfredsen, Charlotte H. ^{[1
]}

Jensen, Soren R. ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark

[2] Royal Bot Gardens, Jodrell Lab, Surrey TW9 3DS, England

来源：

JOURNAL OF NATURAL PRODUCTS | 2014年 / 77卷 / 03期

关键词：

IRIDOID GLUCOSIDES; SCROPHULARIACEAE; CHEMOTAXONOMY; DISINTEGRATION; SYSTEMATICS;

D O I：

10.1021/np400853f

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

From an extract of Manulea corymbosa were isolated four known secoiridoid glucosides (1-4), 10 new monoterpenoid esters of secologanol, namely, manuleosides A I (5-11, 13, and 14) and dimethyl rhodanthoside A (12), and four new phenylpropanoid esters of carbocyclic iridoid glucosides, manucorymbosides I-IV (15-18). Also, the caffeoyl phenylethanoid glycoside verbascoside was isolated. The presence of secoiridoids apparently derived from loganic acid in the family Scrophulariaceae is unprecedented and greatly unexpected.

引用

页码：589 / 595

页数：7

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