Structure and properties of composites of highly crystalline cellulose with polypropylene: Effects of polypropylene molecular weight

被引:48
作者
Qiu, Wulin [1 ]
Endo, Takashi [1 ]
Hirotsu, Takahiro [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Takamatsu, Kagawa 7610395, Japan
关键词
polypropylene (PP); cellulose; molecular weight; composites; mechanical properties;
D O I
10.1016/j.eurpolymj.2005.11.012
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Composite of highly crystalline fibrous cellulose (CE) and polypropylene (PP) of different molecular weights ((M) over bar (w)) was prepared via melting-mixing, maleic anhydride grafted polypropylene (MAPP) was used as a compatibilizer. And the effects of molecular weight of PP on the properties of the composites were investigated. Through the studying of mechanical properties, dynamic mechanical properties, melting and crystallization behaviors, thermo-oxidative properties, water absorption behaviors, and the morphology of the composites, it was found that PP with higher molecular weight revealed stronger interfacial interaction with cellulose in the composites. Compared with the lower molecular weight, the composites derived from higher molecular weight of PP exhibited stronger tensile strength at the same cellulose content. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1059 / 1068
页数:10
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