Facile synthesis of a triptycene-based porous organic polymer with a high efficiency and recyclable adsorption for organic dyes

被引：32
作者：
Li, Yajing [1 ]
Wang, Haijiang [2 ]
Zhao, Weifeng [3 ]
Wang, Xiaoqin [1 ]
Shi, Yidong [2 ]
Fan, Haojun [2 ]
Sun, Hui [1 ]
Tan, Lin [2 ,3 ]
机构：
[1] Sichuan Univ, Coll Architecture & Environm, Chengdu 610065, Sichuan, Peoples R China
[2] Sichuan Univ, Coll Light Ind Text & Food Engn, Chengdu 610065, Sichuan, Peoples R China
[3] Sichuan Univ, Coll Polymer Sci & Engn, Chengdu 610065, Sichuan, Peoples R China
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2019年 / 136卷 / 39期
基金：
中国国家自然科学基金;
关键词：
adsorption; functionalization of polymers; separation techniques; synthesis and processing techniques; GRAPHENE OXIDE; AQUEOUS-SOLUTION; METHYLENE-BLUE; SULFONIC-ACID; CATIONIC DYES; FLY-ASH; REMOVAL; ADSORBENT; FRAMEWORKS; CARBON;
D O I：
10.1002/app.47987
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Water contamination resulting from organic dyes has had severe detrimental effects on human health and environmental tolerance. To address this issue, a delicate strategy for taking host-guest function in porous organic polymers via a facile Friedel-Crafts reaction of triptycene and post-modification was achieved. By means of this route, a sulfonic acid functionalized triptycene-based porous organic polymer (TPOP-SO3H) with a hierarchical structure and a desirable Brunauer-Emmett-Teller value of 1002 m(2)/g was synthesized this study. The TPOP-SO3H material demonstrated a maximum adsorption capacity for methylene blue of 97.1 mg/g. Remarkably, an absorption efficiency of more than 90% of TPOP-SO3H was observed even after five cycles. Therefore, such a hierarchical porous organic polymer can be highly recommended as one type of promising material for the treatment of organic dye-polluted wastewater. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47987.
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页数：10
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