One-pot two-step stannylation/Stille homocoupling of aryl bromides and iodides under solvent-free conditions

被引：7
|
作者：
Gribanov, Pavel S. [1 ,2 ]
Golenko, Yulia D. [1 ]
Topchiy, Maxim A. [1 ,2 ]
Philippova, Anna N. [2 ]
Kirilenko, Nikita Yu. [1 ,2 ]
Krivoshchapov, Nikolai V. [1 ]
Sterligov, Grigorii K. [1 ]
Asachenko, Andrey F. [1 ,2 ]
Bermeshev, Maxim V. [2 ]
Nechaev, Mikhail S. [1 ,2 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
[2] Russian Acad Sci, AV Topchiev Inst Petrochem Synth, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2018年 / 28卷 / 03期
基金：
俄罗斯科学基金会;
关键词：
CROSS-COUPLING REACTIONS; ENANTIOSELECTIVE SYNTHESIS; EFFICIENT SYNTHESIS; ALKENYL HALIDES; SOLAR-CELLS; PALLADIUM; COMPLEXES; SALTS; CHLORIDES; CATALYSTS;
D O I：
10.1016/j.mencom.2018.05.032
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new highly efficient solvent-free method for aryl bromide (iodide) homocoupling comprising the use of Pd(OAc)(2)/PCy3 system in the presence of CsF is suitable for substrates bearing functional groups not tolerant to lithium-, magnesium-, zinc-organic reagents and strong bases.
引用
收藏
页码：323 / 325
页数：3
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