Optical Spectra of Gadolinium(III) Ions in Melts of Alkali Metal Fluorides

被引：1

作者：

Khokhryakov, A. A. ^{[1
]}

Paivin, A. S. ^{[1
]}

Samoilova, M. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Met, Ural Branch, Ekaterinburg 620016, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 64卷 / 06期

关键词：

electronic absorption spectra; coordination sphere; complex groups; BR; CL; NA; LA; CS; LN;

D O I：

10.1134/S0036023619050103

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Optical spectra of MF-GdF3 (M = Li, Na, K, and Cs) and NaF-CsF-GdF3 molten systems are presented. On the basis of spectral data, it has been determined that stable complex groups GdF63- are formed in these melts. In the molten LiF-GdF3 system, the GdF4- group, which decomposes over time, is found along with the GdF63- complex group. It has been suggested that the number of cations in the second coordination sphere of the GdF63- groups decreases from 14 to 13 when passing from the melts of LiF, NaF to KF, CsF.

引用

页码：798 / 800

页数：3

共 50 条

[31] Catalytic Effect of Alkali Metal Ions on the Generation of CO and CO2 during Lignin Pyrolysis: A Theoretical Study
Jiang, Xiaoyan
Han, Yiming
Li, Baojiang
Liu, Ji
Zhou, Guanzheng
Du, Xiaojiao
Wei, Shougang
Meng, Hanxian
Hu, Bin
CATALYSTS, 2024, 14 (08)
[32] Alkali metal ions induced high-quality all-inorganic Cs2AgBiBr6 perovskite films for flexible self-powered photodetectors
Yan, Genghua
Jiang, Bangqi
Xiao, Yao
Zhao, Chuanxi
Yuan, Ye
Liang, Zongcun
APPLIED SURFACE SCIENCE, 2022, 579
[33] Study on electronic and optical properties of alkali metal atoms adsorbed GaAs nanowires by first-principles calculations
Diao, Yu
Liu, Lei
Xia, Sihao
Feng, Shu
Lu, Feifei
SOLID STATE COMMUNICATIONS, 2018, 278 : 42 - 48
[34] Hot-injection synthesis of lead-free pseudo-alkali metal-based perovskite (TlSnX3) nanoparticles with tunable optical properties
Kim, Wooyeon
Koo, Bonkee
Ko, Min Jae
Jung, Heesuk
FRONTIERS IN MATERIALS, 2023, 10
[35] Near-infrared luminescence enhancing by introducing alkali metal ions in Sr2CeO4:Yb3+
Xiao, Quanlan
Dong, Guoping
Qiu, Jianrong
JOURNAL OF LUMINESCENCE, 2014, 147 : 163 - 167
[36] Sb2S3@PPy Coaxial Nanorods: A Versatile and Robust Host Material for Reversible Storage of Alkali Metal Ions
Shi, Yang
Li, Feng
Zhang, Yi
He, Liang
Ai, Qing
Luo, Wen
NANOMATERIALS, 2019, 9 (04):
[37] Structures and Nonlinear Optical Properties of Alkali Metal-Doped t-Bu-calix[4]arene Molecules
Hou Na
Li Ying
Wu Di
Li Zhi-Ru
ACTA PHYSICO-CHIMICA SINICA, 2014, 30 (07) : 1223 - 1229
[38] Optimal balance: alkali metal-doped boron carbide nanosheets achieve superior stability and nonlinear optical responsiveness
Yaqoob, Junaid
Almohamadi, Hamad
Khan, Asim Laeeq
Yasin, Muhammad
Mahmood, Tariq
Ayub, Khurshid
Anwar, Farooq
Joya, Khurram Saleem
Gilani, Mazhar Amjad
RSC ADVANCES, 2024, 14 (42) : 31021 - 31035
[39] Controllable Formation of Heterotrimetallic Coordination Compounds: Systematically Incorporating Lanthanide and Alkali Metal Ions into the Manganese 12-Metallacrown-4 Framework
Azar, Michael R.
Boron, Thaddeus T., III
Lutter, Jacob C.
Daly, Connor I.
Zegalia, Kelcie A.
Nimthong, Ruthairat
Ferrence, Gregory M.
Zeller, Matthias
Kampf, Jeff W.
Pecoraro, Vincent L.
Zaleski, Curtis M.
INORGANIC CHEMISTRY, 2014, 53 (03) : 1729 - 1742
[40] Inorganic electrides of alkali metal doped Zn12O12 nanocage with excellent nonlinear optical response
Khan, Saima
Gilani, Mazhar Amjad
Munsif, Sajida
Muhammad, Shabbir
Ludwig, Ralf
Ayub, Khurshid
JOURNAL OF MOLECULAR GRAPHICS & MODELLING, 2021, 106

← 1 2 3 4 5 →