α-iminoenamido ligands:: A novel structure for transition-metal activation

被引：74

作者：

Kim, YH

Kim, TH

Lee, BY ^{[1
]}

Woodmansee, D

Bu, XH

Bazan, GC

机构：

[1] Ajou Univ, Dept Mol Sci & Technol, Suwon 442749, South Korea

[2] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 15期

关键词：

D O I：

10.1021/om020251b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This communication shows that it is possible to activate nickel complexes containing the alpha-iminoenamide ligand using B(C6F5)(3) or AI(C6F5)(3) to generate catalysts that polymerize ethylene. The polymerization of ethylene using these novel compounds is discussed. The novel activation method is confirmed by the X-ray crystallography studies of the methallyl analogs.

引用

页码：3082 / 3084

页数：3

共 35 条

[1]

[Anonymous], ZIEGLER CATALYSTS

[2]

[Anonymous], ANGEW CHEM

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