Magnetron-sputtered oxidation protection coatings for Mo-Si-B alloys

被引:46
作者
Lange, Annika [1 ]
Braun, Reinhold [1 ]
机构
[1] DLR German Aerosp Ctr, Inst Mat Res, D-51170 Cologne, Germany
关键词
Intermetallics; Sputtered films; SEM; Oxidation; ALUMINUM PACK CEMENTATION; HIGH-RATE DEPOSITION; MOLYBDENUM SILICIDES; RESISTANT COATINGS; BEHAVIOR; BORON; MICROSTRUCTURE; KINETICS; MO5SI3;
D O I
10.1016/j.corsci.2014.03.013
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Oxidation protective Mo-70Al, Mo-37Si-15B and Mo-46Si-24B (at.%) coatings with 5-10 mu m thickness were deposited on Mo-9Si-8B alloys by magnetron sputtering; and their oxidation behavior was studied at 800, 1000 and 1300 degrees C in air. On the Mo-70Al layer a dense aluminum borate scale grew at 800 degrees C; however, this coating rapidly degraded at 1000 degrees C linked to substrate oxidation at uncoated areas. The Mo-37Si-15B and Mo-46Si-24B layers provided oxidation protection to the Mo-Si-B alloy at 800 and 1000 degrees C for up to 100 h due to formation of a borosilicate scale. The latter coating was protective for short times even at 1300 degrees C. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:74 / 84
页数:11
相关论文
共 48 条
[1]   Boron-doped molybdenum silicides for structural applications [J].
Akinc, M ;
Meyer, MK ;
Kramer, MJ ;
Thom, AJ ;
Huebsch, JJ ;
Cook, B .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1999, 261 (1-2) :16-23
[2]   BEHAVIOR OF MOLYBDENUM DIBORIDE IN RESISTIVE THICK-FILM [J].
AKULOVA, LT ;
VLASOVA, MV ;
VOROPAEVA, IV ;
HORPYAKOV, OT .
JOURNAL OF MATERIALS SCIENCE, 1992, 27 (12) :3293-3296
[3]   High Rate Deposition of Magnetic Material by Gas Flow Sputtering [J].
Bandorf, Ralf ;
Bloche, Andre ;
Ortner, Kai ;
Luethje, Holger ;
Jung, Thomas .
PLASMA PROCESSES AND POLYMERS, 2007, 4 :S129-S133
[4]   Solid-solid interactions in pure and Na2O-doped MoO3/Al2O3 system [J].
El-Shobaky, GA ;
Fagal, GA ;
Hassan, NA .
THERMOCHIMICA ACTA, 1998, 311 (1-2) :205-211
[5]  
Fournelle JH, 2000, INST PHYS CONF SER, P425
[6]   ACCELERATED OXIDATION, INTERNAL OXIDATION, INTERGRANULAR OXIDATION, AND PESTING OF INTERMETALLIC COMPOUNDS [J].
GRABKE, HJ ;
MEIER, GH .
OXIDATION OF METALS, 1995, 44 (1-2) :147-176
[7]   OXIDATION OF MOLYBDENUM 550-DEGREES-C TO 1700-DEGREES-C [J].
GULBRANSEN, EA ;
ANDREW, KF ;
BRASSART, FA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1963, 110 (09) :952-959
[8]  
Hansen M., 1958, CONSTITUTION BINARY, P253
[9]   Metallic materials for structural applications beyond nickel-based superalloys [J].
Heilmaier, M. ;
Krueger, M. ;
Saage, H. ;
Roesler, J. ;
Mukherji, D. ;
Glatzel, U. ;
Voelkl, R. ;
Huettner, R. ;
Eggeler, G. ;
Somsen, Ch. ;
Depka, T. ;
Christ, H. -J. ;
Gorr, B. ;
Burk, S. .
JOM, 2009, 61 (07) :61-67
[10]   Solubility of boron in Mo5+ySi3-y [J].
Huebsch, JJ ;
Kramer, MJ ;
Zhao, HL ;
Akinc, M .
INTERMETALLICS, 2000, 8 (02) :143-150