Synthesis, crystal structures and characterization of three novel complexes with N-[2-(2-hydroxybenzylideneamino)ethyl]-4-methyl-benzene-sulfonamide as ligand

被引：14

作者：

Li, Shu-Ni ^{[1
]}

Zhai, Quan-Guo ^{[1
]}

Hu, Man-Cheng ^{[1
]}

Jiang, Yu-Cheng ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Sch Chem & Mat Sci, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 07期

关键词：

N-Tosyl-ethylenediamine; Sulfonamide Schiff base; Supramolecular architecture; Fluorescence; METAL-SALEN COMPLEXES; SCHIFF-BASE LIGANDS; ELECTROCHEMICAL SYNTHESIS; CATALYSTS; DESIGN; METALLOENZYMES; DINUCLEAR; DIIMINE;

D O I：

10.1016/j.ica.2008.10.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the N-tosyl-ethylenediamine and salicylaldehyde forms a new sulfonamide Schiff base N-[2-(2-hydroxybenzylideneamino) ethyl]-4-methyl-benzene-sulfonamide (H2L). Three novel complexes constructed from H2L, namely, [M(HL)(2)] center dot xH(2)O (M = Cu, x = 0 for 1, M = Ni, x = 0 for 2 and M = Zn, x = 1 for 3) have been prepared and characterized via X-ray single-crystal diffraction, elemental analysis, X- ray powder diffraction (XRPD), FT-IR, UV-Vis, TGA and photoluminescence measurements. Complex hydrogen bonds, C-H center dot center dot center dot pi and pi-pi stacking interactions lead 1-3 to present 1-D, 2-D and 3-D supramolecular architectures, respectively. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：2217 / 2221

页数：5

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