Pervaporation Study of Ethylene Glycol Dehydration Through Synthesized (PVA-4A)/Polypropylene Mixed Matrix Composite Membranes

被引：66
作者：
Shahverdi, Mahnaz [1 ]
Baheri, Bahareh [1 ]
Rezakazemi, Mashallah [1 ]
Motaee, Elahe [1 ]
Mohammadi, Toraj [1 ]
机构：
[1] IUST, Res Ctr Membrane Separat Proc, Fac Chem Engn, Tehran, Iran
来源：
POLYMER ENGINEERING AND SCIENCE | 2013年 / 53卷 / 07期
关键词：
SEPARATION PERFORMANCE ANALYSIS; NANOCOMPOSITE MEMBRANES; WATER MIXTURES; GAS SEPARATION; NANOPARTICLES; SIMULATION; ETHER;
D O I：
10.1002/pen.23406
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Poly(vinyl alcohol) (PVA)/zeolite 4A mixed matrix composite membranes supported on polypropylene micro-filtration membranes were prepared by solution casting method and crosslinked with glutaraldehyde to investigate their pervaporation (PV) separation properties of water-ethylene glycol mixtures. Scanning electron microscopy images showed homogeneous distribution of zeolite nanoparticles within the polymer matrix without any visible macroscopic voids at the zeolite-polymer interface. The PV experiments were accomplished to investigate the effects of water concentration (10-40 wt%) and temperature (60-80 degrees C) on separation performance of the membranes. It was found out that 5 wt% loading of the 4A nanoparticles into the PVA matrix is optimal to obtain the best separation performance. The experimental results revealed that loading of zeolite 4A enhanced the membrane performance [both permeation flux (5%) and separation factor (32%) at 5 wt% zeolite loading]. (C) 2012 Society of Plastics Engineers
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收藏
页码：1487 / 1493
页数：7
相关论文
共 32 条
[1]   Mixed matrix membranes prepared from natural rubber/poly(vinyl alcohol) semi-interpenetrating polymer network (NR/PVA semi-IPN) incorporating with zeolite 4A for the pervaporation dehydration of water-ethanol mixtures [J].
Amnuaypanich, S. ;
Patthana, J. ;
Phinyocheep, P. .
CHEMICAL ENGINEERING SCIENCE, 2009, 64 (23) :4908-4918
[2]   Transport through zeolite filled polymeric membranes [J].
Boom, JP ;
Punt, IGM ;
Zwijnenberg, H ;
de Boer, R ;
Bargeman, D ;
Smolders, CA ;
Strathmann, H .
JOURNAL OF MEMBRANE SCIENCE, 1998, 138 (02) :237-258
[3]  
Chon H., 1996, Recent Advances and New Horizons in Zeolite Science and Technology
[4]   Fabrication and characterization of polysulfone/polyimide-zeolite mixed matrix membrane for gas separation [J].
Dorosti, F. ;
Omidkhah, M. R. ;
Pedram, M. Z. ;
Moghadam, F. .
CHEMICAL ENGINEERING JOURNAL, 2011, 171 (03) :1469-1476
[5]   Poly(vinyl alcohol) multilayer mixed matrix membranes for the dehydration of ethanol-water mixture [J].
Guan, HM ;
Chung, TS ;
Huang, Z ;
Chng, ML ;
Kulprathipanja, S .
JOURNAL OF MEMBRANE SCIENCE, 2006, 268 (02) :113-122
[6]   Pervaporation separation of ethylene glycol/water mixtures through surface crosslinked PVA membranes: Coupling effect and separation performance analysis [J].
Guo, Ruili ;
Hu, Changlai ;
Li, Ben ;
Jiang, Zhongyi .
JOURNAL OF MEMBRANE SCIENCE, 2007, 289 (1-2) :191-198
[7]   Acetic Acid/Water Separation by Pervaporation With Silica Filled PDMS Membrane [J].
Hong, Housheng ;
Chen, Longxiang ;
Zhang, Qingwen ;
Zhang, Zheran .
POLYMER ENGINEERING AND SCIENCE, 2011, 51 (05) :819-825
[8]   Pervaporation performance of chitosan-poly(acrylic acid) polyelectrolyte complex membranes for dehydration of ethylene glycol aqueous solution [J].
Hu, Changlai ;
Li, Ben ;
Guo, Ruili ;
Wu, Hong ;
Jiang, Zhongyi .
SEPARATION AND PURIFICATION TECHNOLOGY, 2007, 55 (03) :327-334
[9]   Separation of ethylene glycol-water mixtures using sulfonated poly(ether ether ketone) pervaporation membranes: Membrane relaxation and separation performance analysis [J].
Huang, RYM ;
Shao, PH ;
Feng, X ;
Anderson, WA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (12) :2957-2965
[10]   Pervaporation study of aqueous ethanol solution through zeolite-incorporated multilayer poly(vinyl alcohol) membranes: Effect of zeolites [J].
Huang, Z ;
Guan, HM ;
Tan, WL ;
Qiao, XY ;
Kulprathipanja, S .
JOURNAL OF MEMBRANE SCIENCE, 2006, 276 (1-2) :260-271
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