Synthesis and Crystal Structure of 5-Methoxy-4′-chloro-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol

被引：0

作者：

Yang, Yu-Hua ^{[1
]}

Zhang, Xin-Ying ^{[1
]}

Zhao, Meng-Meng ^{[1
]}

Li, Gang ^{[1
]}

Dong, Xiu-Yan ^{[1
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2014年 / 26卷 / 04期

关键词：

Asymmetrical Salamo-type compound; Synthesis; Crystal structure; HYDROLYTIC KINETIC RESOLUTION; SCHIFF-BASE; COPPER(II) COMPLEXES; CO(SALEN) COMPLEXES; SPECTRAL PROPERTIES; MAGNETIC-PROPERTIES; BISOXIME LIGAND; SALEN; CATALYSTS;

D O I：

10.14233/ajchem.2014.16032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An asymmetrical Salamo-type compound 5-methoxy-4'-chloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol have been synthesized and characterized by single crystal X-ray crystallography. The crystal structure shows that the compound adopts an L-shaped configuration, in which the benzene rings are approximately perpendicular, making a dihedral angle of 84.09(3)degrees. And the molecule contains abundant intramolecular and intermolecular hydrogen bonding interactions. Thus, each molecule links six other molecules into an infinite 3D supramolecular structure by intermolecular hydrogen bonding interactions.

引用

页码：1133 / 1135

页数：3

共 27 条

[1] Oxime-based salen-type tetradentate ligands with high stability against imine metathesis reaction
Akine, S
Taniguchi, T
Dong, WK
Masubuchi, S
Nabeshima, T
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (05) : 1704 - 1711
[2] Synthesis of acyclic tetrakis- and pentakis(N2O2) ligands for single-helical heterometallic complexes with a greater number of winding turns
Akine, Shigehisa
Matsumoto, Takashi
Sairenji, Shiho
Nabeshima, Tatsuya
[J]. SUPRAMOLECULAR CHEMISTRY, 2011, 23 (1-2) : 106 - 112
[3] Polymer-supported chiral Co(salen) complexes: Synthetic applications and mechanistic investigations in the hydrolytic kinetic resolution of terminal epoxides
Annis, DA
Jacobsen, EN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (17) : 4147 - 4154
[4] CRYSTAL AND MOLECULAR-STRUCTURE OF AND MAGNETIC COUPLING IN 2 COMPLEXES CONTAINING GADOLINIUM(III) AND COPPER(II) IONS
BENCINI, A
BENELLI, C
CANESCHI, A
CARLIN, RL
DEI, A
GATTESCHI, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) : 8128 - 8136
[5] Breinbauer R, 2000, ANGEW CHEM INT EDIT, V39, P3604, DOI 10.1002/1521-3773(20001016)39:20<3604::AID-ANIE3604>3.0.CO
[6] 2-9
[7] Lanthanide-containing molecular and supramolecular polymetallic functional assemblies
Bünzli, JCG
Piguet, C
[J]. CHEMICAL REVIEWS, 2002, 102 (06) : 1897 - 1928
[8] Polystyrene and polymethacrylate resin-supported Jacobsen's alkene epoxidation catalyst
Canali, L
Cowan, E
Deleuze, H
Gibson, CL
Sherrington, DC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (13): : 2055 - 2066
[9] Influence of anionic ligands (X) on the nature and magnetic properties of dinuclear LCuGdX3•nH2O complexes (LH2 standing for tetradentate Schiff base ligands deriving from 2-hydroxy-3-methoxybenzaldehyde and X being Cl, N3C2, and CF3COO)
Costes, JP
Dahan, F
Dupuis, A
[J]. INORGANIC CHEMISTRY, 2000, 39 (02) : 165 - 168
[10] Synthesis and second-order nonlinear optical properties of bis(salicylaldiminato)M(II) metalloorganic materials
Di Bella, S
Fragalà, I
[J]. SYNTHETIC METALS, 2000, 115 (1-3) : 191 - 196

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