A family of nanoporous materials based on an amino acid backbone

被引：369

作者：

Vaidhyanathan, Ramanathan ^{[1
]}

Bradshaw, Darren ^{[1
]}

Rebilly, Jean-Noel ^{[1
]}

Barrio, Jorge P. ^{[1
]}

Gould, Jamie A. ^{[1
]}

Berry, Neil G. ^{[1
]}

Rosseinsky, Matthew J. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 39期

基金：

英国工程与自然科学研究理事会;

关键词：

amino acids; chirality; metal-organic frameworks; nanoporous materials; sorption;

D O I：

10.1002/anie.200602242

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) In the pocket: A nanoporous framework with internal surfaces lined with amino acid residues (see structure; Ni cyan, C gray (chiral centers yellow), H white, N blue, O red) is produced by the pillaring of nickel-aspartate layers by 4,4′-bipyridine. The presence of pockets capable of multiple interactions with guest species permits the enantioselective sorption of short-chain diols. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6495 / 6499

页数：5

共 19 条

[1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

MICHAIL, DM ;

ROBSON, R .

NATURE, 1994, 369 (6483) :727-729

[2] [Ni2O(L-Asp)(H2O)2]•4H2O:: A homochiral 1D helical chain hybrid compound with extended Ni-O-Ni bonding [J].

Anokhina, EV ;

Jacobson, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) :3044-3045

[3] COORDINATION BEHAVIOR OF L-ASPARTIC ACID - TERNARY NICKEL(II) COMPLEXES WITH IMIDAZOLES - CRYSTAL AND MOLECULAR-STRUCTURE OF (L-ASPARTATE)TRIS(IMIDAZOLE)NICKEL(II) [J].

BATTAGLIA, LP ;

CORRADI, AB ;

ANTOLINI, L ;

MARCOTRIGIANO, G ;

MENABUE, L ;

PELLACANI, GC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (09) :2407-2411

[4] Permanent microporosity and enantioselective sorption in a chiral open framework [J].

Bradshaw, D ;

Prior, TJ ;

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114

[5] A route to high surface area, porosity and inclusion of large molecules in crystals [J].

Chae, HK ;

Siberio-Pérez, DY ;

Kim, J ;

Go, Y ;

Eddaoudi, M ;

Matzger, AJ ;

O'Keeffe, M ;

Yaghi, OM .

NATURE, 2004, 427 (6974) :523-527

[6]

Dybtesev D.N., 2006, ANGEW CHEM, V118, P930, DOI [DOI 10.1002/ANGE.200503023, 10.1002/ange.200503023]

[7] A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity [J].

Dybtsev, DN ;

Nuzhdin, AL ;

Chun, H ;

Bryliakov, KP ;

Talsi, EP ;

Fedin, VP ;

Kim, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :916-920

[8] A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F ;

Dutour, J ;

Surblé, S ;

Margiolaki, I .

SCIENCE, 2005, 309 (5743) :2040-2042

[9] The chirality, porosity, and ferromagnetism of a 3D nickel glutarate with intersecting 20-membered ring channels [J].

Guillou, N ;

Livage, C ;

Drillon, M ;

Férey, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (43) :5314-5317

[10] Efficient docking of peptides to proteins without prior knowledge of the binding site [J].

Hetényi, C ;

van der Spoel, D .

PROTEIN SCIENCE, 2002, 11 (07) :1729-1737

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