Chemoenzymatic syntheses of the linear triquinane-type sesquiterpenes (+)-hirsutic acid and (-)-complicatic acid

被引：30

作者：

Austin, Kerrie A. B. ^{[1
]}

Banwell, Martin G. ^{[1
]}

Harfoot, Gwion J. ^{[1
]}

Willis, Anthony C. ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Inst Adv Studies, Canberra, ACT 0200, Australia

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 41期

基金：

澳大利亚研究理事会;

关键词：

chemoenzymatic; (-)-complicatic acid; Diels-Alder reaction; cis-1,2-dihydrocatechol; sesquiterpene; triquinane;

D O I：

10.1016/j.tetlet.2006.07.145

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Formal total syntheses of the natural enantiomeric forms of the title sesquiterpenes 1 and 2 have been achieved using, as starting material, the readily available and enantiomerically pure cis-1,2-dihydrocatechol 4 derived from the whole-cell biotransformation of toluene. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：7381 / 7384

页数：4

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