Formation of in situ CB/PET microfibers in CB/PET/PE composites by slit die extrusion and hot stretching

被引:29
作者
Xu, XB
Li, ZM [1 ]
Yu, RZ
Lu, A
Yang, MB
Huang, R
机构
[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Sichuan, Peoples R China
[2] China Acad Engn Phys, Inst Chem Mat, Mianyang 629000, Sichuan, Peoples R China
关键词
carbon black; conductive polymer composite; microfibrillar; mixing; morphology;
D O I
10.1002/mame.200400016
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this present study, the in situ fabrication of a microfibrillar composite based on poly(ethlene terephthalate) (PET), polyethylene (PE), and carbon black (CB) is attempted. PET and CB were first melt mixed. The CB/PET compound and PE were subsequently melt-extrusted through a slit die and then hot stretched. The morphological observation of the as-stretched extrudate indicated that well-defined microfibers of CB/PET compound could be generated at appropriate CB contents and a fixed hot stretch ratio. In addition, CB was always selectivity located in PET. The microfibrillar CB/PET/PE composite has the potential to be a new electrically conductive polymer composite.
引用
收藏
页码:568 / 575
页数:8
相关论文
共 44 条
[1]   DROPLET FIBER TRANSITIONS IN IMMISCIBLE POLYMER BLENDS GENERATED DURING MELT PROCESSING [J].
CHAPLEAU, N ;
FAVIS, BD .
JOURNAL OF MATERIALS SCIENCE, 1995, 30 (01) :142-150
[2]  
CHEREMISINOFF NP, 1999, HDB ENG POLYM MAT
[3]   DEFORMATION OF A DROP IN A GENERAL TIME-DEPENDENT FLUID FLOW [J].
COX, RG .
JOURNAL OF FLUID MECHANICS, 1969, 37 :601-&
[4]   Droplet deformation in immiscible polymer blends during transient uniaxial elongational flow [J].
Delaby, I ;
Ernst, B ;
Froelich, D ;
Muller, R .
POLYMER ENGINEERING AND SCIENCE, 1996, 36 (12) :1627-1635
[5]   A STUDY ON POLYMER BLENDING MICRORHEOLOGY .4. THE INFLUENCE OF COALESCENCE ON BLEND MORPHOLOGY ORIGINATION [J].
ELMENDORP, JJ ;
VANDERVEGT, AK .
POLYMER ENGINEERING AND SCIENCE, 1986, 26 (19) :1332-1338
[6]   A STUDY ON POLYMER BLENDING MICRORHEOLOGY [J].
ELMENDORP, JJ .
POLYMER ENGINEERING AND SCIENCE, 1986, 26 (06) :418-426
[7]  
Evstatiev M, 2000, ADV POLYM TECH, V19, P249, DOI 10.1002/1098-2329(200024)19:4<249::AID-ADV2>3.3.CO
[8]  
2-I
[9]   In situ fibrillar reinforced PET/PA-6/PA-66 blend [J].
Evstatiev, M ;
Schultz, JM ;
Fakirov, S ;
Friedrich, K .
POLYMER ENGINEERING AND SCIENCE, 2001, 41 (02) :192-204
[10]   MICROFIBRILLAR REINFORCED COMPOSITES - NEW MATERIALS FROM POLYMER BLENDS [J].
FAKIROV, S ;
EVSTATIEV, M .
ADVANCED MATERIALS, 1994, 6 (05) :395-398