Perfluorovinyl-metal derivatives: A new one-pot synthesis

被引：38

作者：

Banger, KK ^{[1
]}

Brisdon, AK ^{[1
]}

Gupta, A ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a605732b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The one-pot reaction of the CFC replacement 1,1,1,2-tetrafluoroethane (CF3CFH2, HFC-134a) with 2 equiv. of butyllithium in diethyl ether at -78 degrees C followed by the addition of main-group or transition-metal halides results in good yields of the corresponding metal-perfluorovinyl compounds of high purity.

引用

页码：139 / 140

页数：2

共 5 条

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[4] ACTIVATION OF CARBON FLUORINE BONDS BY METAL-COMPLEXES
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OSTERBERG, CE
[J]. CHEMICAL REVIEWS, 1994, 94 (02) : 373 - 431
[5] PREPARATION AND SOME REACTIONS OF TRIFLUOROVINYLLITHIUM
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