NaB3O5•0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

被引：37
作者：
Wang, Jun-Hua [1 ]
Cheng, Jian-Wen [2 ]
Wei, Qi [3 ]
He, Huan [1 ]
Yang, Bai-Feng [1 ]
Yang, Guo-Yu [1 ,3 ]
机构：
[1] Beijing Inst Technol, Sch Chem, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
[2] Zhejiang Normal Univ, Key Lab, Minist Educ Adv Catalysis Mat, Inst Phys Chem, Jinhua 321004, Zhejiang, Peoples R China
[3] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 25期
基金：
中国国家自然科学基金;
关键词：
Open frameworks; Borates; Chirality; Topochemistry; Luminescence; 24-RING CHANNELS; CRYSTAL-STRUCTURE; HELICAL CHAINS; LEAD BORATE; PHOSPHITE; ALKALINE; ALUMINOBORATE; CHEMISTRY; ZEOLITES; SULFATES;
D O I：
10.1002/ejic.201402318
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new cluster open framework borates, NaB3O5 center dot 0.5H(2)O (1) and NH4NaB6O10 (2) have been made under solvothermal conditions and characterized by IR, emission, and diffuse reflectance spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The common structural features contain the oxoboron cluster building units, B3O7 and B6O13 cluster units for 1 and 2, in which the B3O7 and B6O13 clusters act as 4- and 6- connected nodes to further link each other, resulting in chiral qtz and achiral pcu nets, respectively.
引用
收藏
页码：4079 / 4083
页数：5
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