Facile fabrication of TiO2/Graphene composite foams with enhanced photocatalytic properties

被引:27
作者
Men, Xiaoju [1 ]
Wu, Yilun [1 ]
Chen, Haobin [1 ]
Fang, Xiaofeng [1 ]
Sun, Hang [2 ]
Yin, Shengyan [1 ]
Qin, Weiping [1 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Jilin, Peoples R China
[2] Jilin Univ, Coll Biol & Agr Engn, Key Lab Bion Engn, Minist Educ, Changchun 130022, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
Photocatalysis; Self-supporting; Graphene foam; TiO2; HIGH-PERFORMANCE SUPERCAPACITOR; ORGANIC-DYE REMOVAL; GRAPHENE SHEETS; OXIDE; FILMS; TIO2; ELECTRODES; NANOSHEETS; HYBRID; DEGRADATION;
D O I
10.1016/j.jallcom.2017.01.353
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A self-supporting macroporous graphene foam was prepared by template method. This foam which was fabricated by reduced graphene oxide (rGO) has good conductivity, and it also has large surface both in the foam interior and outside surface. The surface can offer a good platform to introduce active materials into the foam. TiO2 nanorods were grown on the foam framework using hydrothermal synthesized method. Due to a well-ordered macroporous structure and high conductivity of the reduced graphene oxide scaffold, the light utilizing in the composite TiO2/rGO foam will increase, and the photoinduced electron also transports quickly to the substrate. These advantages resulted in a better photocurrent response. Furthermore, the well photo induced electron transports will also lead to better photocatalytic degradation property. The enhanced absorption performance, photocurrent response, photocatalytic degradation property of composite TiO2/rGO foam will make this foam a promising material for practical applications in the environmental protection field. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:251 / 257
页数:7
相关论文
共 39 条
[1]   Supramolecular Polymerization Promoted In Situ Fabrication of Nitrogen-Doped Porous Graphene Sheets as Anode Materials for Li-Ion Batteries [J].
Ai, Wei ;
Jiang, Jian ;
Zhu, Jianhui ;
Fan, Zhanxi ;
Wang, Yanlong ;
Zhang, Hua ;
Huang, Wei ;
Yu, Ting .
ADVANCED ENERGY MATERIALS, 2015, 5 (15)
[2]   Visible active nanocrystalline N-doped anatase TiO2 particles for photocatalytic mineralization studies [J].
Barkul, R. P. ;
Koli, V. B. ;
Shewale, V. B. ;
Patil, M. K. ;
Delekar, S. D. .
MATERIALS CHEMISTRY AND PHYSICS, 2016, 173 :42-51
[3]   Graphene oxide-assisted synthesis and photocatalytic hydrogen production of mix-phase titanium dioxide (TiO2) nanosheets [J].
Cai, Fanpeng ;
Tang, Yubin ;
Shen, Hao ;
Wang, Chao ;
Ren, Ao ;
Xiao, Lisong ;
Gu, Wei ;
Shi, Weidong .
CRYSTENGCOMM, 2015, 17 (05) :1086-1091
[4]   Self-cleaning, broadband and quasi-omnidirectional antireflective structures based on mesocrystalline rutile TiO2 nanorod arrays [J].
Cai, Jinguang ;
Ye, Jianfeng ;
Chen, Suyue ;
Zhao, Xiaowei ;
Zhang, Dayong ;
Chen, Shuai ;
Ma, Yurong ;
Jin, Song ;
Qi, Limin .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (06) :7575-7581
[5]  
Chen ZP, 2011, NAT MATER, V10, P424, DOI [10.1038/NMAT3001, 10.1038/nmat3001]
[6]   3D Graphene-Cobalt Oxide Electrode for High-Performance Supercapacitor and Enzymeless Glucose Detection [J].
Dong, Xiao-Chen ;
Xu, Hang ;
Wang, Xue-Wan ;
Huang, Yin-Xi ;
Chan-Park, Mary B. ;
Zhang, Hua ;
Wang, Lian-Hui ;
Huang, Wei ;
Chen, Peng .
ACS NANO, 2012, 6 (04) :3206-3213
[7]   Hybrid structure of zinc oxide nanorods and three dimensional graphene foam for supercapacitor and electrochemical sensor applications [J].
Dong, Xiaochen ;
Cao, Yunfa ;
Wang, Jing ;
Chan-Park, Mary B. ;
Wang, Lianhui ;
Huang, Wei ;
Chen, Peng .
RSC ADVANCES, 2012, 2 (10) :4364-4369
[8]   Multifunctional Graphene/Platinum/Nafion Hybrids via Ice Templating [J].
Estevez, Luis ;
Kelarakis, Antonios ;
Gong, Qianming ;
Da'as, Eman Husni ;
Giannelis, Emmanuel P. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (16) :6122-6125
[9]   Convenient Recycling of 3D AgX/Graphene Aerogels (X = Br, Cl) for Efficient Photocatalytic Degradation of Water Pollutants [J].
Fan, Yingying ;
Ma, Weiguang ;
Han, Dongxue ;
Gan, Shiyu ;
Dong, Xiandui ;
Niu, Li .
ADVANCED MATERIALS, 2015, 27 (25) :3767-3773
[10]   2D and 3D graphene materials: Preparation and bioelectrochemical applications [J].
Gao, Hongcai ;
Duan, Hongwei .
BIOSENSORS & BIOELECTRONICS, 2015, 65 :404-419