Acid-catalyzed formation of free radicals in the reaction of hydroperoxides with ketones

被引：8
|
作者：
Petrov, LV [1 ]
Solyanikov, VM [1 ]
机构：
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA
来源：
RUSSIAN CHEMICAL BULLETIN | 1996年 / 45卷 / 02期
关键词：
oxidation; acid catalysis; free radicals; acetonitrile; p-toluenesulfonic acid; tert-butyl hydroperoxide; cyclohexanone;
D O I：
10.1007/BF01433968
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics of formation of free radicals in the cyclohexanone (CH)-tert-butyl-hydroperoxide (TBHP)-para-toluenesulfonic acid (PTSA) system in acetonitrile was studied. The stoichiometry of the reaction corresponds to the consumption of two TBHP molecules per ketone molecule, whereas the yield of free radicals is similar to 20 % based on the TBHP reacted.
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页码：340 / 345
页数：6
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