Catalytic conversion of urea to biuret: A catalyst screening study

被引：8

作者：

Park, Dong Ryul ^{[1
]}

Kim, Heesoo ^{[1
]}

Jung, Ji Chul ^{[1
]}

Shin, Min Seung ^{[2
]}

Han, Sang Jin ^{[2
]}

Song, In Kyu ^{[1
]}

机构：

[1] Seoul Natl Univ, Sch Chem & Biol Engn, Inst Chem Proc, Seoul 151744, South Korea

[2] Dongjin Semichem Corp, Seoul 121836, South Korea

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2009年 / 26卷 / 04期

关键词：

Biuret; Catalytic Conversion of Urea; Catalyst Screening; OXIDATIVE DEHYDROGENATION; N-BUTENE; CO9FE3BI1MO12O51; PERFORMANCE; OXYGEN;

D O I：

10.1007/s11814-009-0164-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Biuret was synthesized from urea in a batch reactor using various homogeneous and heterogeneous catalysts, with the aim of searching for efficient catalyst in converting non-catalytic reaction to catalytic reaction. For this purpose, zeolite, heteropolyacid, organic acid and base, multicomponent bismuth molybdate, and multicomponent bismuth molybdate-alumina mixed catalysts were tested. It was revealed that the performance of catalytic reaction was better than that of non-catalytic reaction in the synthesis of biuret from urea. Among the homogeneous acid and base catalysts tested, thionyl chloride (SOCl2) showed the best catalytic performance. Among the heterogeneous catalysts tested, on the other hand, a mixed catalyst comprising multicomponent bismuth molybdate (Co8Fe3Bi1Mo12O50) and alumina showed the best catalytic performance.

引用

页码：990 / 993

页数：4

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