Lewis base-catalyzed transformation of α,β-unsaturated aldehydes to saturated carboxylic acids, esters and amides

被引：25

作者：

Kawabata, H ^{[1
]}

Hayashi, M ^{[1
]}

机构：

[1] Kobe Univ, Fac Sci, Dept Chem, Kobe, Hyogo 6578501, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 32期

基金：

日本学术振兴会;

关键词：

Lewis base; alpha; beta-unsaturated aldehyde; carboxylic acid;

D O I：

10.1016/S0040-4039(02)01133-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of alpha,beta-unsaturated aldehydes such as (E)-cinnamaldehyde and 2- or 4-methoxycinnamaldehyde with trimethylsilyl cyanide in the presence of a catalytic amount of a Lewis base such as TTMPP and DBU afforded the corresponding saturated carboxylic acids after hydrolysis. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：5645 / 5647

页数：3

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