Crystal Structure and NMR Study of Tetrakis(acetonitrile)silver(I) Fluorosulfonate [Ag(CH3CN)4]+[SO3F]-

被引：5

作者：

Doertbudak, Can-Carlo ^{[1
]}

Lux, Karin ^{[1
]}

Kornath, Andreas ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2014年 / 69卷 / 03期

关键词：

Crystal Structure; Silver(I); Fluorosulfonate; NMR; Acetonitrile; ACID; PERCHLORATE; SALTS;

D O I：

10.5560/ZNB.2014-3287

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound [Ag(CH3CN)(4)](+)[SO3F](-) crystallizes in the orthorhombic space group Pna2(1), a = 24.383(24), b = 8.632 (11), c = 20.755 (17) angstrom, V = 4368(6) angstrom(3), Z = 12, with three independent formula units in the unit cell. A comparison with the isostructural compound [Ag(CH3CN)(4)](+)[ClO4](-) is given. The salt has also been characterized by solution H-1 and F-19 NMR spectroscopy and the data compared to that of fluorosulfonic acid.

引用

页码：373 / 375

页数：3

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